Heimaeyite

Na3Al(SO4)3
IMA status
  • Approved
IMA symbol
Hme
Also known as
  • Heimaeyiet
  • IMA2023-127a

Where it forms, where it's found

Geological setting

Fumarolic vent

Type locality
Eldfell Volcano
  1. Heimaey Island
  2. Vestmannaeyjar archipelago (Westman islands)
  3. Vestmannaeyjar
  4. Southern Region
  5. Iceland

63.4336°, -20.2489°

1recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Translucent
Colour
orange

These observations apply for the natural sample that contained some Fe replacing Al. Pure synthetic Na3Al(SO4)3 is colourless, and its streak is white.

Streak
yellowish
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
2.783 g/cm³

Optical

Notes

The calculated mean refractive index, using the Gladstone–Dale relationship, is 1.5222.

Crystallography

Crystal system
Trigonal
Space group
#80
Cell parameters
a = 13.4326(9) Å · c = 8.9818(7) Å
Z
6
Type-locality form

formed as microscopic rounded aggregates (<50 µm) and rounded grains (<10 µm) mixed with tiny needles of koryakite and a mineral phase with an NaMgAl(SO4)3 composition

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
49.98%
16SSulfurSulfur332.06096.180
25.04%
11NaSodiumSodium322.99068.970
17.96%
13AlAluminiumAluminium126.98226.982
7.02%
Total384.120100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From Mindat formula

Synonyms

  • Heimaeyiet
  • IMA2023-127a

In other languages

German
Heimaeyit · IMA 2023-127a

Classification

Strunz
10th ed.

7.AA

  • 7SulfatesClass
  • 7.ASulfates (selenates, etc.) without additional anions, without H2ODivision
  • 7.AAWith small cationsGroup
  • 7.AAHeimaeyiteSpecies

Literature, links & citation

Citations
  1. Bernard, Jean, Couchot, Pierre, Theobald, Francois (1970): Preparation and radiocrystallographic study of double sulfates of formula M3+M3+(SO4)3. Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques 270 (12), 1119-1122. (In French.)
  2. 1989Martínez-Lope, M.J., Zamora, J., García-Clavel, M.E. (1989) Oxysalt-metal double reactions in the solid state: Na3Al(SO4)3-Mg. Thermochimica Acta, 153. 105-111 doi:10.1016/0040-6031(89)85426-7DOI: 10.1016/0040-6031(89)85426-7
  3. 2005Colina, Fernando G., Costa, Jose (2005) High-Temperature Reaction of Kaolin with Sodium Hydrogen Sulfate. Industrial & Engineering Chemistry Research, 44 (13). 4495-4500 doi:10.1021/ie030273dDOI: 10.1021/ie030273d
  4. 2025Balić-Žunić, T., Garavelli, A., Mitolo, D., Nestola, F., Pamato, M. G., Rasmussen, M. B., Jølnæs, M. B. (2025) Heimaeyite, Na₃Al(SO₄)₃, a new mineral from the fumaroles on Eldfell volcano, Iceland. European Journal of Mineralogy, 37 (1). 79-89 doi:10.5194/ejm-37-79-2025DOI: 10.5194/ejm-37-79-2025
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Heimaeyite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/heimaeyite-471431},
  note      = {Accessed 2026-05-11}
}