Henmilite

Ca2Cu[B(OH)4]2(OH)4
IMA status
  • Approved
IMA symbol
Hen
Discovered
1981
IMA approved
1981
Also known as
  • Henmiliet
  • IMA1981-050

Where it forms, where it's found

Geological setting

In pentahydroborite veins at a deposit of marble and contact-metamorphosed limestone / skarn.

Type locality
Fuka mine
  1. Fuka
  2. Bitchū
  3. Takahashi City
  4. Okayama Prefecture
  5. Japan

34.7882°, 133.4429°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101.5 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Blue-violet
Streak
Very pale violet to nearly white
Tenacity
fragile
Density
2.51 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 58° · 2V calc = 56°
Refractive index
1.585 – 1.615
Surface relief
Moderate
Principal indices
nα 1.585 · nβ 1.608 · nγ 1.615
Pleochroism
Strong

X = pale pink, Y = pale purple, and Z = very pale blue

Dispersion
small
Notes

Inclined extinction

Michel-Lévy diagramhighlighted lineδ = 0.0300
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]300 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation300 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 5.7617(5) Å · b = 7.9774(6) Å · c = 5.6488(4) Å
Cell angles
α = 109.611(6) ° · β = 91.473(7) ° · γ = 83.686(7) °
Ratio a:b:c
1 : 1.385 : 0.980
Z
1
Morphology

Well developed (100) and (010) pinacoids

Type-locality form

Anhedral masses and rarely as euhedral crystals up to 0.2 mm growing on the surface of, and within, pentahydroborite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
51.97%
20CaCalciumCalcium240.07880.156
21.70%
29CuCopperCopper163.54663.546
17.20%
5BBoronBoron210.81021.620
5.85%
1HHydrogenHydrogen121.00812.096
3.28%
Total369.406100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Henmiliet
  • IMA1981-050

In other languages

French
Henmilite
German
Henmilit · Henmilite · IMA1981-050
Italian
Henmilite
Japanese
逸見石
Russian
Хенмилит

Classification

Strunz
10th ed.

6.AC.30

  • 6BoratesClass
  • 6.AMonoboratesDivision
  • 6.ACB(O,OH)4, without and with additional anions; 1(T), 1(T)+OH, etcGroup
  • 6.AC.30HenmiliteSpecies
Dana
8th ed.

26.01.05.01

  • 26Hydrated Borates Containing Hydroxyl or HalogenClass
  • 26.01MonoboratesType
  • 26.01.05— unnamed intermediate level —Group
  • 26.01.05.01HenmiliteSpecies
CIM

9.3.25

  • 9BoratesClass
  • 9.3Borates of Ca and SrGroup
  • 9.3.25HenmiliteSpecies

Literature, links & citation

Citations
  1. 1986Nakai, I., Okada, H., Masutomi, K., Koyama, E., Nagashima, K. (1986) Henmilite, Ca2Cu(OH)4[B(OH)4]2, a new mineral from Fuka, Okayama Prefecture, Japan. American Mineralogist, 71 (9-10) 1234-1239
  2. 1992Kusachi, I. (1992) New data on mineralogical properties of henmilite. Kobutsugaku Zasshi: 21(3): 127-130.
  3. 1996Grew, Edward S.; Anovitz, Lawrence M. - Eds. (1996) Boron - Mineralogy, Petrology and Geochemistry. Reviews in Mineralogy Vol. 33. Mineralogical Society of America p.862
  4. 2005(2005) Henmilite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2013Frost, Ray L., Xi, Yunfei (2013) Vibrational spectroscopy of the borate mineral henmilite Ca2Cu[B(OH)4]2(OH)4. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 103. 356-360 doi:10.1016/j.saa.2012.11.009DOI: 10.1016/j.saa.2012.11.009
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Henmilite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/henmilite-1866},
  note      = {Accessed 2026-05-11}
}