Hexahydroborite

Ca[B(OH)4]2 · 2H2O
IMA status
  • Approved
IMA symbol
Hhb
Discovered
1976
IMA approved
1977
Also known as
  • Hexahydroboriet
  • Hexahydroborita
  • IMA1977-015

Where it forms, where it's found

Geological setting

Boron-rich skarn deposits in metasomatized limestone.

Type locality
Solongo B deposit
  1. Ozernoe ore cluster
  2. Yeravninsky District
  3. Buryatia
  4. Russia

52.9994°, 111.6878°

3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless
Streak
White
Cleavage
Perfect

Perfect normal to the plane 12° from Z. Also an imperfect cleavage.

Density
1.84 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 83° · 2V calc = 82°
Refractive index
1.498 – 1.51
Surface relief
Moderate
Principal indices
nα 1.498 · nβ 1.503 · nγ 1.51
Dispersion
very weak
Extinction
X ∧ c = 14°.
Michel-Lévy diagramhighlighted lineδ = 0.0120
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]120 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation120 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#10
Cell parameters
a = 8 Å · b = 6.64 Å · c = 8.01 Å
Cell angles
β = 104.21 °
Ratio a:b:c
1 : 0.830 : 1.001
Type-locality form

Aggregates of flattened prismatic colorless crystals to 0.5 mm.

Comment

A axis may be 16.011 (Fuka)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1015.999159.990
68.44%
20CaCalciumCalcium140.07840.078
17.14%
5BBoronBoron210.81021.620
9.25%
1HHydrogenHydrogen121.00812.096
5.17%
Total233.784100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Hexahydroboriet
  • Hexahydroborita
  • IMA1977-015

In other languages

German
Hexahydroborit · IMA 1977-015
Italian
Esaidroborite · Hexahydroborite

Classification

Strunz
10th ed.

6.AC.25

  • 6BoratesClass
  • 6.AMonoboratesDivision
  • 6.ACB(O,OH)4, without and with additional anions; 1(T), 1(T)+OH, etcGroup
  • 6.AC.25HexahydroboriteSpecies
Dana
8th ed.

26.01.04.01

  • 26Hydrated Borates Containing Hydroxyl or HalogenClass
  • 26.01MonoboratesType
  • 26.01.04— unnamed intermediate level —Group
  • 26.01.04.01HexahydroboriteSpecies
CIM

9.3.16

  • 9BoratesClass
  • 9.3Borates of Ca and SrGroup
  • 9.3.16HexahydroboriteSpecies

Literature, links & citation

Citations
  1. 1964Ozol, Y., Vimba, S., Ievins, A. (1964) The crystal structure of calcium monoborate Ca[B(OH)4]2·2H2O. Soviet Physics - Crystallography: 9: 22-25.
  2. 1971Sedlacek, P., Dornberger-Schiff, K. (1971) An OD-Disordered modification of the calcium monoborate dihydrate Ca[B(OH)4]2·2H2O. Acta Crystallographica: B27: 1532-1541.
  3. 1976Simonov, M.A., Yamanova, N.A., Kazanskaya, E.V., Egorov-Tismenko, Y.K., Belov, N.V. (1976) Crystal structure of a new natural calcium borate, hexahydroborite CaB2O4·6H2O=Ca[B(OH)]2·2H2O. Soviet Physics - Doklady: 21: 314-316.
  4. 1976Simonov, M.A., Yamnova, N.A., Kazanskaya, E.V., Egorov-Tismenko, Y.K., Belov, N.V. (1976) Crystal structure of Ca(B(OH)4)2(H2O)2. Doklady Akademii Nauk SSSR: 228: 1337-1340.
  5. 1977Fleischer, Michael, Cabri, Louis J., Pabst, and Adolf (1977) New mineral names. American Mineralogist, 62 (11-12) 1259-1262
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hexahydroborite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hexahydroborite-1892},
  note      = {Accessed 2026-05-11}
}