Hexathioplumbite

[Pb4(OH)4]Pb(S2O3)3
IMA status
  • Approved
IMA symbol
Htpb
Also known as
  • Hexathioplumbiet
  • IMA2021-092

Where it forms, where it's found

Geological setting

"highly unusual secondary assemblage that comprises a variety of rare Pb-Zn-Cu sulfates, thiosulfates, and carbonates"

Type locality
Redmond Mine
  1. Waterville Lake
  2. Haywood County
  3. North Carolina
  4. USA

35.6802°, -83.0186°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Streak
white
Tenacity
brittle
Cleavage
None Observed

curved fracture

Density
5.531 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.995 – 2.005
Surface relief
Very high
Principal indices
nω 2.005 · nε 1.995
Michel-Lévy diagramhighlighted lineδ = 0.0100
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]100 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation100 nm
Order1st order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
#104
Cell parameters
a = 10.721(1) Å · c = 8.6541(6) Å
Type-locality form

prisms, to ca. 1 mm

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead5207.2001036.000
71.93%
8OOxygenOxygen1315.999207.987
14.44%
16SSulfurSulfur632.060192.360
13.35%
1HHydrogenHydrogen41.0084.032
0.28%
Total1440.379100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Hexathioplumbiet
  • IMA2021-092

In other languages

German
Hexathioplumbit · IMA 2021-092

Classification

Strunz
10th ed.

7.JA

  • 7SulfatesClass
  • 7.JThiosulfatesDivision
  • 7.JAThiosulfates of PbGroup
  • 7.JAHexathioplumbiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 2022(2022) Hexathioplumbite. Handbook of Mineralogy. Mineralogical Society of America
  2. 2022Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2022) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 65. European Journal of Mineralogy, 34 (1) 143-148 doi:10.5194/ejm-34-143-2022 DOI: 10.5194/ejm-34-143-2022
  3. 2023Kampf, Anthony R.; Smith, Jason B.; Hughes, John M.; Ma, Chi; Emproto, Christopher (2023) New Minerals from the Redmond Mine, North Carolina, USA: II. Cubothioplumbite and Hexathioplumbite, Two New Minerals Containing the Cubane-Like [Pb4(OH)4]4+ Structural Unit. The Canadian Journal of Mineralogy and Petrology, 61 (3). 623-633 doi:10.3749/2200070DOI: 10.3749/2200070
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hexathioplumbite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hexathioplumbite-55763},
  note      = {Accessed 2026-05-11}
}