Hilarionite

Fe3+2(SO4)(AsO4)(OH) · 6H2O
IMA status
  • Approved
IMA symbol
Hrn
IMA approved
2011
Also known as
  • Hilarioniet
  • IMA2011-089

Where it forms, where it's found

Geological setting

In the oxidation zone of a sulfide-rich ore-body.

Type locality
Hilarion Mine
  1. Kamariza Mines (Kamareza Mines)
  2. Agios Konstantinos (Kamariza)
  3. Lavreotiki
  4. East Attica
  5. Attica
  6. Greece

37.7200°, 24.0120°

4recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Light green (with typically olive or greyish tint) to light yellowish-green · grey-green
Tenacity
flexible
Fracture
Irregular/Uneven · Splintery
Density
2.40 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = large°
Refractive index
1.575 – 1.64
Surface relief
Moderate
Principal indices
nα 1.575 · nγ 1.64
Michel-Lévy diagramhighlighted lineδ = 0.0650
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]650 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation650 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 18.53(4) Å · b = 17.43(3) Å · c = 7.56(1) Å
Cell angles
β = 94.06(15) °
Ratio a:b:c
1 : 0.941 : 0.408
Unit cell volume
2436 ų
Z
8
Morphology

Spherulites; near-parallel or divergent aggregates of very thin, curved fibers.

Type-locality form

Spherulites (up to 1 mm in size) and bunches of prismatic to acicular «individuals» (up to 0.5 mm long) that are in fact near-parallel or divergent aggregates of very thin, curved fibers up to 0.3 mm long and usually lesser than 2 µm thick.

Comment

Space group C2, Cm or C2/m.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1515.999239.985
50.87%
26FeIronIron255.845111.690
23.67%
33AsArsenicArsenic174.92274.922
15.88%
16SSulfurSulfur132.06032.060
6.80%
1HHydrogenHydrogen131.00813.104
2.78%
Total471.761100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Hilarioniet
  • IMA2011-089

In other languages

German
Hilarionit · IMA 2011-089
Spanish
hilarionita
Italian
hilarionite

Classification

Strunz
10th ed.

8.CE.60

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CEWith only medium-sized cations, RO4:H2O about 1:2.5Group
  • 8.CE.60HilarioniteSpecies

Literature, links & citation

Citations
  1. 2012Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2012) New minerals and nomenclature modifications approved in 2012. CNMNC Newsletter No 12. Mineralogical Magazine, 76 (1) 151-155 doi:10.1180/minmag.2012.076.1.151 DOI: 10.1180/minmag.2012.076.1.151
  2. 2014(2014) Hilarionite. Handbook of Mineralogy. Mineralogical Society of America
  3. 2014Camara, F.; Gatta, G. D.; Uvarova, Y.; Gagne, O. C.; Belakovskiy, D. I. (2014) New Mineral Names. American Mineralogist, 99 (7). 1511-1518 doi:10.2138/am.2014.646DOI: 10.2138/am.2014.646
  4. 2014Pekov, I. V., Chukanov, N. V., Yapaskurt, V. O., Rusakov, V. S., Belakovsky, D. I., Turchkova, A. G., Voudouris, P., Magganas, A., Katerinopoulos, A. (2014) Hilarionite, Fe 2 3+ (SO4)(AsO4)(OH) · 6H2O, a new supergene mineral from Lavrion, Greece. Geology of Ore Deposits, 56 (7) 567-575 doi:10.1134/s1075701514070101DOI: 10.1134/s1075701514070101
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hilarionite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hilarionite-42410},
  note      = {Accessed 2026-05-11}
}