Hillebrandite

Ca2SiO3(OH)2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Hil
Discovered
1908
Also known as
  • Hillebrandiet

Where it forms, where it's found

Geological setting

High temperature contact metamorphic mineral in marbles

Type locality
Terneras Mine
  1. Velardeña
  2. Velardeña District
  3. Cuencamé Municipality
  4. Durango
  5. Mexico

25.0667°, -103.7333°

19recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105 – 5.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
White · colorless · very pale greenish white.
Streak
White
Tenacity
brittle
Cleavage
Distinct/Good

(010)

Density
2.66 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 51 – 60° · 2V calc = 64°
Refractive index
1.598 – 1.614
Surface relief
Moderate
Principal indices
nα 1.598 – 1.607 · nβ 1.603 – 1.610 · nγ 1.603 – 1.614
Birefringence
0.007-0.009
Dispersion
strong
Extinction
Z=c
Michel-Lévy diagramhighlighted lineδ = 0.0070
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]70 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation70 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#50
Cell parameters
a = 3.63 Å · b = 16.31 Å · c = 11.82 Å
Cell angles
β = 90 °
Ratio a:b:c
1 : 4.493 : 3.256
Z
12
Morphology

Rod-like to fibrous

Type-locality form

White fibers in dense aggregates

Comment

Non-standard setting Cmc21; also momoclinic with beta = 90 degrees

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
20CaCalciumCalcium240.07880.156
42.13%
8OOxygenOxygen515.99979.995
42.05%
14SiSiliconSilicon128.08528.085
14.76%
1HHydrogenHydrogen21.0082.016
1.06%
Total190.252100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ti
  • Al
  • Fe
  • Mn
  • Mg
  • Na
  • K

Synonyms

  • Hillebrandiet

In other languages

German
Hillebrandit
Italian
Hillebrandite
Chinese
针硅钙石

Classification

Strunz
10th ed.

9.DG.40

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DGInosilicates with 3-periodic single and multiple chainsGroup
  • 9.DG.40HillebranditeSpecies
Dana
8th ed.

65.02.03.01

  • 65Inosilicates Single-width, Unbranched Chains, (w=1)Class
  • 65.02Single-Width Unbranched Chains, W=1 with chains P=3Type
  • 65.02.03— unnamed intermediate level —Group
  • 65.02.03.01HillebranditeSpecies
CIM

14.5.14

  • 14Silicates not Containing AluminumClass
  • 14.5Silicates of CaGroup
  • 14.5.14HillebranditeSpecies

Literature, links & citation

Citations
  1. 1908Wright F E (1908) On three contact minerals from Valardeña, Durango, Mexico. (Gehlenite, spurrite and hillebrandite). American Journal of Science 176, 545-554
  2. 1953Claringbull, G.F. (1953) Mineralogical Society (London). American Mineralogist: 38: 734-737.
  3. 1995Dai, Y., Post, J.E. (1995) Crystal structure of hillebrandite: A natural analogue of calcium silicate hydrate (CSH) phases in Portland cement. American Mineralogist: 80: 841-844.
  4. 1996Xu, H., Buseck, P.R. (1996) TEM investigation of the domain structure and superstructure in hillebrandite, Ca2SiO3(OH)2. American Mineralogist: 81: 1371-1374.
  5. 2001(2001) Hillebrandite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hillebrandite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hillebrandite-1904},
  note      = {Accessed 2026-05-11}
}