Holdawayite

Mn2+6(CO3)2(OH)7(Cl,OH)
IMA status
  • Approved
IMA symbol
Hdw
Discovered
1986
IMA approved
1986
Also known as
  • Holdawayiet
  • IMA1986-001

Where it forms, where it's found

Geological setting

Tectonically intercalated manganese and iron ores, which are locally dominated by carbonate- and silicate-facies rocks rather than by the more usual hausmannite ores.

Type locality
Kombat Mine
  1. Kombat
  2. Otavi Constituency
  3. Otjozondjupa Region
  4. Namibia

-19.7081°, 17.7033°

3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Light to bright pink

It gradually changes to a brown color on exposure and in some cases has developed a thin black sooty coating that masks the true color

Streak
Light pink
Tenacity
brittle
Cleavage
Perfect

(100)

Density
3.19 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 12 – 18° · 2V calc = 16°
Refractive index
1.644 – 1.721
Surface relief
High
Principal indices
nα 1.644 · nβ 1.719 · nγ 1.721
Pleochroism
Non-pleochroic
Dispersion
relatively strong
Extinction
X = b; Z ∧ c = 45(3)° in the obtuse angle of beta.
UV response
None
Michel-Lévy diagramhighlighted lineδ = 0.0770
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]770 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation770 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 23.437(5) Å · b = 3.3137(3) Å · c = 16.618(6) Å
Cell angles
β = 111.15(2) °
Ratio a:b:c
1 : 0.141 : 0.709
Z
4
Morphology

Granular aggregates or massive. Fibrous, elongated along [001].

Type-locality form

Subhedral crystals approximately 2 cm in diameter.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese654.938329.628
53.07%
8OOxygenOxygen1415.999223.986
36.06%
17ClChlorineChlorine135.45035.450
5.70%
6CCarbonCarbon212.01124.022
3.87%
1HHydrogenHydrogen81.0088.064
1.30%
Total621.150100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Holdawayiet
  • IMA1986-001

In other languages

German
Holdawayit · IMA 1986-001
Italian
Holdawayite
Chinese
霍尔达维石

Classification

Strunz
10th ed.

5.BA.20

  • 5CarbonatesClass
  • 5.BCarbonates with additional anions, without H2ODivision
  • 5.BAWith Cu, Co, Ni, Zn, Mg, MnGroup
  • 5.BA.20HoldawayiteSpecies
Dana
8th ed.

16b.04.02.02

  • 16bHydrated Carbonates Containing Hydroxyl or HalogenClass
  • 16b.04AmBn(XO3)pZqxH2O & with (m+n):p = 3:1Type
  • 16b.04.02— unnamed intermediate level —Group
  • 16b.04.02.02HoldawayiteSpecies
CIM

11.12.2

  • 11CarbonatesClass
  • 11.12Carbonates of MnGroup
  • 11.12.2HoldawayiteSpecies

Literature, links & citation

Citations
  1. 1988Peacor, Donald R., Essene, Eric J., Rouse, Roland C., Dunn, Pete J., Nelen, Joseph A., Grice, Joel D., Innes, John, Knorring, Oleg Von (1988) Holdawayite, a new manganese hydroxyl-carbonate from the Kombat mine, Namibia. American Mineralogist, 73 (5-6) 632-636
  2. 1988Peacor, Donald R., Rouse, Roland C. (1988) Holdawayite, Mn6(CO3)2(OH)7(Cl,OH), a structure containing anions in zeolite-like channels. American Mineralogist, 73 (5-6) 637-642
  3. 1991Dunn, Pete J. (1991) Rare Minerals of the Kombat Mine. The Mineralogical Record, 22 (6) 421-425
  4. 2005(2005) Holdawayite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2011Mernagh, Terrence P., Kamenetsky, Vadim S., Kamenetsky, Maya B. (2011) A Raman microprobe study of melt inclusions in kimberlites from Siberia, Canada, SW Greenland and South Africa. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 80 (1) 82-87 doi:10.1016/j.saa.2011.01.034DOI: 10.1016/j.saa.2011.01.034
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Holdawayite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/holdawayite-1919},
  note      = {Accessed 2026-05-11}
}