Huizingite-(Al)

(NH4)9Al3(SO4)8(OH)2 · 4H2O
IMA status
  • Approved
IMA symbol
Hui-Al
IMA approved
2015
Also known as
  • Huizingiet-(Al)
  • IMA2015-014

Where it forms, where it's found

Geological setting

as for carlsonite: natural fire of an oil-bearing shale

Type locality
Huron Shale burn site
  1. Huron River
  2. Huron County
  3. Ohio
  4. USA

41.2781°, -82.6742°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
light greenish-yellow
Streak
white
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
2.026 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 40° · 2V calc = 37°
Refractive index
1.543 – 1.563
Surface relief
Moderate
Principal indices
nα 1.543 · nβ 1.545 · nγ 1.563
Pleochroism

pale yellow (X), almost colourless (Y & Z); X > Y ~ Z

Dispersion
strong (r > v)
Michel-Lévy diagramhighlighted lineδ = 0.0200
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]200 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation200 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 9.7093(3) Å · b = 10.4341(3) Å · c = 10.7027(8) Å
Cell angles
α = 77.231(5) ° · β = 74.860(5) ° · γ = 66.104(5) °
Ratio a:b:c
1 : 1.075 : 1.102
Unit cell volume
948.73 ų
Z
1
Morphology

Observed crystal forms: (100), (010), (110)

Twinning

not observed

Type-locality form

tabular to bladed crystals, flattening on (100) , up to ca. 0.25 mm (in max. dimension), in drusy aggregates

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3815.999607.962
54.39%
16SSulfurSulfur832.060256.480
22.94%
7NNitrogenNitrogen914.007126.063
11.28%
13AlAluminiumAluminium326.98280.946
7.24%
1HHydrogenHydrogen461.00846.368
4.15%
Total1117.819100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe(III)

Synonyms

  • Huizingiet-(Al)
  • IMA2015-014

In other languages

German
Huizingit-(Al) · IMA 2015-014
Italian
huizingite-(Al)

Classification

Strunz
10th ed.

7.DF.52

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DFWith large and medium-sized cationsGroup
  • 7.DF.52Huizingite-(Al)Species

Literature, links & citation

Citations
  1. 2015Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2015) New minerals and nomenclature modifications approved in 2015, CNMNC Newsletter No 25. Mineralogical Magazine, 79 (3) 529-535 doi:10.1180/minmag.2015.079.3.02DOI: 10.1180/minmag.2015.079.3.02
  2. 2016Kampf, Anthony R., Richards, R. Peter, Nash, Barbara P., Murowchick, James B., Rakovan, John F. (2016) Carlsonite, (NH4)5Fe3+3O(SO4)6·7H2O, and huizingite-(Al), (NH4)9Al3(SO4)8(OH)2·4H2O, two new minerals from a natural fire in an oil-bearing shale near Milan, Ohio. American Mineralogist, 101 (9) 2095-2107 doi:10.2138/am-2016-5680DOI: 10.2138/am-2016-5680
  3. 2017(2017) Huizingite-(Al). Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Huizingite-(Al) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/huizingite-al-46635},
  note      = {Accessed 2026-05-11}
}