Hydrohalite

NaCl · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Hhl
Discovered
1847
Also known as
  • Bihydrate
  • Hydrohaliet
  • Hydrohalita
  • +1 more

Where it forms, where it's found

Geological setting

Fluid inclusions

Type locality
Hallein - Bad Dürrnberg salt mine
  1. Hallein
  2. Hallein District
  3. Salzburg
  4. Austria

47.6673°, 13.0912°

22recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
Colorless to white
Density
1.65 g/cm³

Optical

Optical type
Biaxial
Extinction
Extinction 35° from a prism face; length-slow.
Anisotropism
moderately strong
Tropism
Anisotropic

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 6.3313(3) Å · b = 10.1178(9) Å · c = 6.5029(6) Å
Cell angles
β = 114.407(7) °
Ratio a:b:c
1 : 1.598 : 1.027
Z
4
Comment

Space group probable - synthetic

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
17ClChlorineChlorine135.45035.450
37.52%
8OOxygenOxygen215.99931.998
33.87%
11NaSodiumSodium122.99022.990
24.34%
1HHydrogenHydrogen41.0084.032
4.27%
Total94.470100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Bihydrate
  • Hydrohaliet
  • Hydrohalita
  • Natriumchloridhydrat

In other languages

French
hydrohalite
German
Hydrohalit
Italian
hydrohalite · Idrohalite
Russian
Гидрогалит
Arabic
هيدروهاليت

Classification

Strunz
10th ed.

3.BA.05

  • 3HalidesClass
  • 3.BSimple halides, with H2ODivision
  • 3.BAM:X = 1:1 and 2:3Group
  • 3.BA.05HydrohaliteSpecies
Dana
8th ed.

09.01.02.01

  • 09Normal HalidesClass
  • 09.01AXType
  • 09.01.02— unnamed intermediate level —Group
  • 09.01.02.01HydrohaliteSpecies
CIM

8.1.4

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.1Halides of the alkali metals and ammoniumGroup
  • 8.1.4HydrohaliteSpecies

Literature, links & citation

Citations
  1. Neues Jahrbuch für Mineralogie, Geognosie, Geologie und Petrefaktenkunde: II: 12-13.
  2. 1847Hausmann, J.F.L. (1847) Zehnte Klasse. Chloride. 2. Hydrohalit. Handbuch der Mineralogie, 2, 1458-1459.
  3. 1877Quenstedt, F.A. (1877) Handbuch der Mineralogie. 623.
  4. 1909Poljenow, B. (1909) Über die Bildung von Chlornatrium- hydrat in der Kempen djaiskschen Salzquelle im Jakutskschen Gebiete.
  5. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hydrohalite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hydrohalite-1975},
  note      = {Accessed 2026-05-11}
}