Hydrotungstite

WO2(OH)2 · H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Htgs
Discovered
1940
Also known as
  • Hydrotungstenite
  • Hydrotungstiet

Where it forms, where it's found

Type locality
San Antonio de Calacalani mine
  1. Cercado Province
  2. Oruro
  3. Bolivia
20recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Dark green · becoming yellowish on exposure to air
Cleavage
Imperfect/Fair

(010), imperfect

Density
4.60 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 52° · 2V calc = 54°
Refractive index
1.7 – 2.04
Surface relief
Very high
Principal indices
nα 1.70 · nβ 1.95 · nγ 2.04
Pleochroism
Visible

X = colorless; Y = yellow-green; Z = dark green.

Dispersion
relatively strong: r < v
Michel-Lévy diagramhighlighted lineδ = 0.3400
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]3400 nm7th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation3400 nm
Order7th order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P2/m
Cell parameters
a = 7.379(5) Å · b = 6.901(5) Å · c = 3.748(5) Å
Cell angles
β = 90.33(12) °
Ratio a:b:c
1 : 0.935 : 0.508
Z
2
Twinning

Polysynthetic, may be grid-like On (210)

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
74WTungstenTungsten1183.840183.840
68.63%
8OOxygenOxygen515.99979.995
29.86%
1HHydrogenHydrogen41.0084.032
1.51%
Total267.867100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Hydrotungstenite
  • Hydrotungstiet

In other languages

German
Hydrotungstit
Italian
Hydrotungstite · Idrotungstite

Classification

Strunz
10th ed.

4.FJ.15

  • 4OxidesClass
  • 4.FHydroxides (without V or U)Division
  • 4.FJHydroxides with H2O +- (OH); corner-sharing octahedraGroup
  • 4.FJ.15HydrotungstiteSpecies
Dana
8th ed.

49.01.01.01

  • 49Hydrated Molybdates and TungstatesClass
  • 49.01Acid Hydrated Molybdates and TungstatesType
  • 49.01.01— unnamed intermediate level —Group
  • 49.01.01.01HydrotungstiteSpecies
CIM

7.15.6

  • 7Oxides and HydroxidesClass
  • 7.15Oxides of Mo and WGroup
  • 7.15.6HydrotungstiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1944Kerr, Paul F., Young, Ford (1944) Hydrotungstite, a new mineral from Oruro, Bolivia. American Mineralogist, 29 (5-6) 192-210
  2. 1981Sahama, Th. G. (1981) The secondary tungsten minerals, a review. The Mineralogical Record, 12 (2) 81-87
  3. 1987Daniel M F, Desbat B and Lassegues J C (1987) Infrared and Raman study of WO3 tungsten trioxides and WO3,xH2O tungsten trioxide hydrates. Journal of Solid State Chemistry 67, 235-247
  4. 2005(2005) Hydrotungstite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2008Kaduc, J. A. & Sentmann, J. B. (2008): Crystal structure of synthetic hydrotungstite, WO2(OH)2(H2O). Acta Crystallogr. A64, C545. [Poster abstract]
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hydrotungstite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hydrotungstite-1988},
  note      = {Accessed 2026-05-11}
}