Hylbrownite

Na3MgP3O10 · 12H2O
IMA status
  • Approved
IMA symbol
Hbw
IMA approved
2010
Also known as
  • Hylbrowniet
  • IMA2010-054

Where it forms, where it's found

Geological setting

Within a seam; formed after the arsenate assemblage, within hypergene ore-bodies related likely to granite intrusion within metasediments.

Type locality
Dome Rock Copper Mine
  1. Boolcoomatta Reserve (Boolcoomata Station)
  2. Pastoral Unincorporated Area
  3. South Australia
  4. Australia

-31.9017°, 140.4606°

2recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
Colourless to white
Streak
White
Tenacity
brittle
Cleavage
Distinct/Good

parallel to (001) and to (100)

Fracture
Irregular/Uneven
Density
1.81 g/cm³

Optical

Optical type
Biaxial (-) · 2V calc = 82.2°
Refractive index
1.39 – 1.446
Surface relief
Low
Principal indices
nα 1.390 · nβ 1.421 · nγ 1.446
Pleochroism
Non-pleochroic
UV response
none
Michel-Lévy diagramhighlighted lineδ = 0.0560
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]560 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation560 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 14.722(3) Å · b = 9.240(2) Å · c = 15.052(3) Å
Cell angles
β = 90.01(3) °
Ratio a:b:c
1 : 0.628 : 1.022
Unit cell volume
2047.5 ų
Z
4
Morphology

Thin prismatic to acicular. Observed forms include (010), (100), (001), (210), (201).

Type-locality form

Thin prismatic to acicular in habit and are elongate along [001], in aggregates and sprays; the crystals are up to 0.12 x 0.02 mm; forms observed: (010), (100), (001), (210), (201).

Comment

Space group P21/n.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2215.999351.978
62.59%
15PPhosphorusPhosphorus330.97492.922
16.52%
11NaSodiumSodium322.99068.970
12.27%
12MgMagnesiumMagnesium124.30524.305
4.32%
1HHydrogenHydrogen241.00824.192
4.30%
Total562.367100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ca

Synonyms

  • Hylbrowniet
  • IMA2010-054

In other languages

German
Hylbrownit · IMA 2010-054
Italian
hylbrownite

Classification

Strunz
10th ed.

8.FC.X

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.FPolyphosphates, Polyarsenates, [4]-PolyvanadatesDivision
  • 8.FCPolyphosphates, etc., with H2O onlyGroup
  • 8.FC.XHylbrowniteSpecies

Literature, links & citation

Citations
  1. 2011Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2011) New minerals and nomenclature modifications approved in 2010, CNMNC Newsletter No 7. Mineralogical Magazine, 75 (1) 27-31 doi:10.1180/minmag.2011.075.1.27 DOI: 10.1180/minmag.2011.075.1.27
  2. 2013Elliott, P., Brugger, J., Caradoc-Davies, T., Pring, A. (2013) Hylbrownite, Na3MgP3O10·12H2O, a new triphosphate mineral from the Dome Rock Mine, South Australia: description and crystal structure. Mineralogical Magazine, 77 (3) 385-398 doi:10.1180/minmag.2013.077.3.11DOI: 10.1180/minmag.2013.077.3.11
  3. 2016(2016) Hylbrownite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hylbrownite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hylbrownite-41135},
  note      = {Accessed 2026-05-11}
}