Irhtemite

Ca4Mg(AsO4)2(AsO3OH)2 · 4H2O
IMA status
  • Approved
IMA symbol
Irh
Discovered
1972
Also known as
  • IMA1971-034
  • Irhtemiet

Where it forms, where it's found

Geological setting

Dehydration product of picropharmacolite in hydrothermal veins.

Type locality
Ightem Mine (Irhtem Mine
  1. Irtem Mine)
  2. Ightem
  3. Tansifte Caïdat
  4. Agdz Cercle
  5. Zagora Province
  6. Drâa-Tafilalet Region
  7. Morocco

30.4890°, -6.6633°

8recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Transparent
Colour
Colorless · white · pale rose
Streak
White
Density
3.09 g/cm³

Optical

Optical type
Biaxial (+)
Refractive index
1.634 – 1.642
Surface relief
Moderate
Principal indices
nα 1.634 · nγ 1.642
Dispersion
strong
Extinction
Extinction angle 25°.
Notes

Elongation negative.

Michel-Lévy diagramhighlighted lineδ = 0.0080
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]80 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation80 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 16.736(5) Å · b = 9.483(3) Å · c = 10.840(5) Å
Cell angles
β = 97.25 °
Ratio a:b:c
1 : 0.567 : 0.648
Z
4
Type-locality form

Spherulites 0.5-1 mm in diameter.

Comment

Point Group: n.d.; Space Group: n.d.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2015.999319.980
39.29%
33AsArsenicArsenic474.922299.688
36.80%
20CaCalciumCalcium440.078160.312
19.69%
12MgMagnesiumMagnesium124.30524.305
2.98%
1HHydrogenHydrogen101.00810.080
1.24%
Total814.365100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1971-034
  • Irhtemiet

In other languages

German
IMA 1971-034 · Irhtemit
Italian
Irhtemite

Classification

Strunz
10th ed.

8.CG.55

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CGWith large and medium-sized cations, RO4:H2O = 1:1Group
  • 8.CG.55IrhtemiteSpecies
Dana
8th ed.

39.02.05.01

  • 39Hydrated Acid Phosphates, Arsenates and VanadatesClass
  • 39.02(AB)5[HXO4]2[XO4]2.xH2OType
  • 39.02.05— unnamed intermediate level —Group
  • 39.02.05.01IrhtemiteSpecies
CIM

20.2.19

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.2Arsenates of Be, Mg, Ca or BaGroup
  • 20.2.19IrhtemiteSpecies

Literature, links & citation

Citations
  1. 1972Pierrot, Roland, Schubnel, Henri-Jean (1972) L'irhtemite, un nouvel arséniate hydraté de calcium et de magnésium. Bulletin de Minéralogie, 95 (3) 365-370 doi:10.3406/bulmi.1972.6690DOI: 10.3406/bulmi.1972.6690
  2. 1974Fleischer, Michael (1974) New mineral names. American Mineralogist, 59 (1-2). 208-212
  3. 2005(2005) Irhtemite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Irhtemite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/irhtemite-2043},
  note      = {Accessed 2026-05-11}
}