Junitoite

CaZn2Si2O7 · H2O
IMA status
  • Approved
IMA symbol
Jit
Discovered
1976
Also known as
  • IMA1975-042
  • Junitoiet

Where it forms, where it's found

Geological setting

Contact metamorphosed zinc orebody.

Type locality
Christmas Mine
  1. Christmas
  2. Banner Mining District
  3. Gila County
  4. Arizona
  5. USA

33.0583°, -110.7458°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless

Sometimes milky white to pale lavender due to alteration.

Streak
White
Tenacity
very brittle
Cleavage
Very Good

(010) very good,(100) and (101) are poor.

Breaks somewhat like mica in that the plates separate easily by breaking using a sharp point.

Fracture
Micaceous
Density
3.5 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 86° · 2V calc = 88°
Refractive index
1.656 – 1.672
Surface relief
High
Principal indices
nα 1.656 · nβ 1.664 · nγ 1.672
Birefringence
0.016
Pleochroism
Non-pleochroic
Dispersion
r < v, very weak
Extinction
X = b; Y = a; Z = c.
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0160
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]160 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation160 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#16
Cell parameters
a = 12.51 Å · b = 6.31 Å · c = 8.56 Å
Ratio a:b:c
1 : 0.504 : 0.684
Z
4
Morphology

Crystals to 5mm with hemimorphic development. c (001), b (010), k (101), p (111), r (131), -r (131), -g (191). (Viscinal forms may show herringbone pattern ["whishbone"]).

Type-locality form

Randomly oriented colorless to lavender platy crystals up to 5 x 0.5 mm.

Comment

Cell re-set from original

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
30ZnZincZinc265.380130.760
36.63%
8OOxygenOxygen815.999127.992
35.85%
14SiSiliconSilicon228.08556.170
15.73%
20CaCalciumCalcium140.07840.078
11.23%
1HHydrogenHydrogen21.0082.016
0.56%
Total357.016100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1975-042
  • Junitoiet

In other languages

French
Junitoite
German
IMA 1975-042 · Junitoit
Italian
Junitoite
Japanese
順伊藤石
Chinese
水硅锌钙石

Classification

Strunz
10th ed.

9.BD.15

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BDSi2O7 groups, with additional anions; cations in tetrahedral [4] and greater coordinationGroup
  • 9.BD.15JunitoiteSpecies
Dana
8th ed.

56.02.01.01

  • 56Sorosilicates Si2o7 Groups, with Additional O, Oh, F and H2oClass
  • 56.02Si2O7 Groups and O, OH, F, and H2O with cations in [4] and/or >[4] coordinationType
  • 56.02.01— unnamed intermediate level —Group
  • 56.02.01.01JunitoiteSpecies
CIM

14.7.17

  • 14Silicates not Containing AluminumClass
  • 14.7Silicates of Ba, Sr and ZnGroup
  • 14.7.17JunitoiteSpecies

Literature, links & citation

Citations
  1. 1968Ito, Jun (1968) Synthesis of some lead calcium zinc silicates. American Mineralogist, 53 (1-2) 231-240
  2. 1976Williams, Sidney A. (1976) Junitoite, a new hydrated calcium zinc silicate from Christmas, Arizona. American Mineralogist, 61 (11-12) 1255-1258
  3. 1985Hamilton, R. D., Finney, J. J. (1985) The structure of junitoite, CaZn2Si2O2 · H2O. Mineralogical Magazine, 49 (350) 91-95 doi:10.1180/minmag.1985.049.350.13 DOI: 10.1180/minmag.1985.049.350.13
  4. 2001(2001) Junitoite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2012Yang, Hexiong, Jenkins, Neil G., Downs, Robert T. (2012) Redetermination of junitoite, CaZn2Si2O7·H2O. Acta Crystallographica Section E Structure Reports Online, 68 (10) 73 doi:10.1107/s1600536812037622 DOI: 10.1107/s1600536812037622
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Junitoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/junitoite-2123},
  note      = {Accessed 2026-05-11}
}