Kalicinite

KH(CO3)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Kcn
Discovered
1865
Also known as
  • Kalicine
  • Kaliciniet
  • Kalicit
  • +1 more

Where it forms, where it's found

Geological setting

Under a dead tree as a decomposition product of recent origin.

Type locality
Chippis
  1. Sierre
  2. Valais
  3. Switzerland
3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless · white · yellowish
Density
2.168 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 81° · 2V calc = 82°
Refractive index
1.38 – 1.578
Surface relief
Low
Principal indices
nα 1.380 · nβ 1.482 · nγ 1.578
Dispersion
r < v weak
Michel-Lévy diagramhighlighted lineδ = 0.1980
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1980 nm4th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1980 nm
Order4th order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/a
Cell parameters
a = 15.1725(11) Å · b = 5.6283(5) Å · c = 3.7110(4) Å
Cell angles
β = 104.631 °
Ratio a:b:c
1 : 0.371 : 0.245
Z
4
Morphology

Fine-crystalline aggregates. Crystals shiort prismatic (artificial material).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen315.99947.997
47.94%
19KPotassiumPotassium139.09839.098
39.05%
6CCarbonCarbon112.01112.011
12.00%
1HHydrogenHydrogen11.0081.008
1.01%
Total100.114100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Kalicine
  • Kaliciniet
  • Kalicit
  • Potassium Bicarbonate

In other languages

French
kalicine · kalicinite
German
Kalicinit
Italian
Kalicinite

Classification

Strunz
10th ed.

5.AA.20

  • 5CarbonatesClass
  • 5.ACarbonates without additional anions, without H2ODivision
  • 5.AAAlkali carbonatesGroup
  • 5.AA.20KaliciniteSpecies
Dana
8th ed.

13.01.02.01

  • 13Acid CarbonatesClass
  • 13.01MiscellaneousType
  • 13.01.02— unnamed intermediate level —Group
  • 13.01.02.01KaliciniteSpecies
CIM

11.1.8

  • 11CarbonatesClass
  • 11.1Carbonates of the alkali metals and ammoniumGroup
  • 11.1.8KaliciniteSpecies

Literature, links & citation

Citations
  1. 1823Brooke, H.J. (1823) On the crystalline forms of artifical salts. Annals of Philosophy, London, New Series: 6: 38-43 (42). (synthetic)
  2. 1865Pisani, F. (1865) Sur la kalicine, nouvelle espèce minérale de Chypis en Valais. Comptes Rendus Hebdomadaires des Séances de l'Académie des Sciences, 60, 918-919.
  3. 1888Landero, Carlos F. De (1888) Sinopsis Mineralógica ó catálogo descriptivo de los Minerales. 528pp., Mexico: 255 (as Kalicit).
  4. 1893Ochsenius (1893) Zeitschrift für praktische Geologie, Berlin, hale a.S.: 198.
  5. 1898Groth, F. (1898) Tabellarische Übersicht der Einfachen Mineralien (4th ed.). Friedrich Vieweg und Sohn.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Kalicinite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/kalicinite-2305},
  note      = {Accessed 2026-05-11}
}