Kalithallite

K3Tl3+Cl6 · 2H2O
IMA status
  • Approved
IMA symbol
Kth
IMA approved
2017
Also known as
  • IMA2017-044
  • Kalithalliet

Where it forms, where it's found

Geological setting

From a relatively low-temperature (70–150°C) fumarole. Formed through interactions involving high-temperature sublimate minerals, volcanic gas and atmospheric water vapour.

Type locality
Northern fumarole field
  1. First scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.6833°, 160.2333°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Transparent
Colour
Colourless · white · pale cream · pale beige

Colourless in individuals and white to pale cream-coloured or pale beige in aggregates.

Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
3.01 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.656 – 1.662
Surface relief
High
Principal indices
nω 1.662 · nε 1.656
Pleochroism
Non-pleochroic
Michel-Lévy diagramhighlighted lineδ = 0.0060
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]60 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation60 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
I4/mmm
Cell parameters
a = 15.9336(6) Å · c = 18.1018(8) Å
Z
14
Morphology

Lamellar (flattened on [001]) to tabular crystals combined in open-work aggregates. Sometimes with a stepped surface. The major form is the pinacoid (001). Other forms observed include the tetragonal prisms (100) and (010), as well as non-indexed dipyramidal faces.

Parting
None observed.
Type-locality form

Lamellar to tabular crystals up to 5 × 30 × 40 μm, sometimes with a stepped surface, combined in open-work aggregates up to 1 mm across.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
17ClChlorineChlorine635.450212.700
37.29%
81TlThalliumThallium1204.380204.380
35.83%
19KPotassiumPotassium339.098117.294
20.56%
8OOxygenOxygen215.99931.998
5.61%
1HHydrogenHydrogen41.0084.032
0.71%
Total570.404100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2017-044
  • Kalithalliet

In other languages

German
IMA 2017-044 · Kalithallit

Classification

Strunz
10th ed.

3.CJ.30

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.CJWith MX6 complexes; M = Fe, Mn, CuGroup
  • 3.CJ.30KalithalliteSpecies

Literature, links & citation

Citations
  1. 2017Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2017) New minerals and nomenclature modifications approved in 2017, CNMNC Newsletter No 39. Mineralogical Magazine, 81 (5) 1279-1286 doi:10.1180/minmag.2017.081.072DOI: 10.1180/minmag.2017.081.072
  2. 2022(2022) Kalithallite. Handbook of Mineralogy. Mineralogical Society of America
  3. 2023Pekov, Igor V., Krzhizhanovskaya, Maria G., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Sidorov, Evgeny G., Zhegunov, Pavel S. (2023) Kalithallite, K3Tl3+Cl6⋅2H2O, a new mineral with trivalent thallium from the Tolbachik volcano, Kamchatka, Russia. Mineralogical Magazine, 87 (2) 186-193 doi:10.1180/mgm.2022.124DOI: 10.1180/mgm.2022.124
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Kalithallite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/kalithallite-52146},
  note      = {Accessed 2026-05-11}
}