Kapundaite

CaNaFe3+4(PO4)4(OH)3 · 5H2O
IMA status
  • Approved
IMA symbol
Kpd
Discovered
1980
IMA approved
2009
Also known as
  • IMA2009-047
  • Kapundaiet

Where it forms, where it's found

Geological setting

Phosphorite horizons in Cambrian marine sediments that were modified by metamorphism, followed by weathering and secondary enrichment.

Type locality
Tom's Quarry
  1. Koonunga
  2. Light Regional Council
  3. South Australia
  4. Australia

-34.3600°, 138.9870°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Pale to golden yellow
Streak
Yellow
Tenacity
flexible
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
2.93 g/cm³

Optical

Optical type
Uniaxial (+) · 2V calc = 64.7°
Refractive index
1.717 – 1.79
Surface relief
High
Principal indices
nα 1.717 · nβ 1.737 · nγ 1.790
Pleochroism
Weak

X = nearly colorless, Y = light brown, Z = pale brown.

Dispersion
None observed
Extinction
Z = b, Y ≈ c.
UV response
Not fluorescent
Notes

Absorption: Y > Z > X.

Michel-Lévy diagramhighlighted lineδ = 0.0730
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]730 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation730 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 6.317(5) Å · b = 7.698(6) Å · c = 9.768(7) Å
Cell angles
α = 105.53(1) ° · β = 99.24(2) ° · γ = 90.09(2) °
Ratio a:b:c
1 : 1.219 : 1.546
Unit cell volume
451.2 ų
Z
1
Morphology

Type material: The primary form is (100). Other forms in the [010] zone are present, but cannot be measured. Flattened terminations suggest that (010) is also present.

Twinning

None observed.

Type-locality form

Cavernous aggregates of fibers to several cm. Crystals are very thin flattened fibers to a few mm long, but only a few microns thick. The fibers occur in subparallel bundles, compact compact radial sprays, and feathery curving masses.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2415.999383.976
47.56%
26FeIronIron455.845223.380
27.67%
15PPhosphorusPhosphorus430.974123.896
15.34%
20CaCalciumCalcium140.07840.078
4.96%
11NaSodiumSodium122.99022.990
2.85%
1HHydrogenHydrogen131.00813.104
1.62%
Total807.424100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2009-047
  • Kapundaiet

In other languages

German
IMA 2009-047 · Kapundait
Italian
kapundaite

Classification

Strunz
10th ed.

8.DH.80

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
  • 8.DH.80KapundaiteSpecies
Dana
8th ed.

42.11.28

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.11(AB)3(XO4)2Zq·xH2OType
  • 42.11.28— unnamed intermediate level —Group
  • 42.11.28KapundaiteSpecies

Literature, links & citation

Citations
  1. 2010Mills, S. J., Birch, W. D., Kampf, A. R., Christy, A. G., Pluth, J. J., Pring, A., Raudsepp, M., Chen, Y. S. (2010) Kapundaite, (Na,Ca)2Fe3+4(PO4)4(OH)3·5H2O, a new phosphate species from Toms quarry, South Australia: Description and structural relationship to mélonjosephite. American Mineralogist, 95 (5) 754-760 doi:10.2138/am.2010.3466 DOI: 10.2138/am.2010.3466
  2. 2021(2021) Kapundaite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Kapundaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/kapundaite-39673},
  note      = {Accessed 2026-05-11}
}