Karibibite

Fe3+3(As3+O2)4(As3+2O5)(OH)
IMA status
  • Approved
IMA symbol
Kab
Discovered
1973
Also known as
  • IMA1973-007
  • Karibibiet

Where it forms, where it's found

Geological setting

Pegmatite, secondary after loellingite

Type locality
Karibib Constituency
  1. Erongo Region
  2. Namibia

-21.9381°, 15.8544°

19recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Tenacity
flexible
Density
4.07 g/cm³

Optical

Optical type
Biaxial (-)
Refractive index
1.96 – 2.1
Surface relief
Very high
Principal indices
nα 1.96 · nβ 2.1 · nγ 2.1
Pleochroism
Weak
Dispersion
strong
UV response
Fluorescent yellow under 253 nm excitation
Notes

Absorption parallel to the fiber axis is slightly higher (light brownish yellow) than perpendicular to it (straw yellow). The optic axial plane and γ-direction are parallel to the fiber axis.

Michel-Lévy diagramhighlighted lineδ = 0.1400
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1400 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1400 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Pnma
Cell parameters
a = 7.2558(3) Å · b = 27.992(1) Å · c = 6.5243(3) Å
Ratio a:b:c
1 : 3.858 : 0.899
Unit cell volume
1325.1 ų
Z
8
Type-locality form

Radiating groups of sharply pointed, spindle-shaped bundles of fibers up to 1 mm in length.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic674.922449.532
53.38%
8OOxygenOxygen1415.999223.986
26.60%
26FeIronIron355.845167.535
19.90%
1HHydrogenHydrogen11.0081.008
0.12%
Total842.061100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1973-007
  • Karibibiet

In other languages

German
IMA 1973-007 · Karibibit
Spanish
Karibibita
Italian
Karibibite

Classification

Strunz
10th ed.

4.JA.15

  • 4OxidesClass
  • 4.JArsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodatesDivision
  • 4.JAArsenites, antimonites, bismuthites; without additional anions, without H2OGroup
  • 4.JA.15KaribibiteSpecies
Dana
8th ed.

07.10.02.01

  • 07Multiple OxidesClass
  • 07.10AB4X9Type
  • 07.10.02— unnamed intermediate level —Group
  • 07.10.02.01KaribibiteSpecies
CIM

23.18

  • 23ArsenitesClass
  • 23.18— unnamed intermediate level —Group
  • 23.18KaribibiteSpecies

Literature, links & citation

Citations
  1. 1973Knorring, Oleg V, Sahama, Th.G, Rehtijärvi, Pentti (1973) Karibibite, a new FeAs mineral from South West Africa. Lithos, 6 (3) 265-271 doi:10.1016/0024-4937(73)90087-xDOI: 10.1016/0024-4937(73)90087-x
  2. 1974Fleischer, Michael; Mandarino, Joseph A (1974) New mineral names. American Mineralogist, 59 (3-4). 381-384
  3. 1980Schmetzer, K., Tremmel, G., Bartelke, W. (1980) Eine Paragenese seltener Minerale aus Bou-Azzer, Marokko: Parasymplesit, Symplesit, Schneiderhöhnit, Karibibit. Neues Jahrbuch für Mineralogie, Abhandlungen: 138: 94-108.
  4. 2005(2005) Karibibite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2016Anthony, John W., Bideaux, Richard A., Bladh, Kenneth W., Nichols, Monte C. - Eds. (2016) Handbook of Mineralogy. https://www.handbookofmineralogy.org/
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Karibibite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/karibibite-2159},
  note      = {Accessed 2026-05-11}
}