Kentrolite

Pb2Mn3+2O2(Si2O7)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ken
Discovered
1880
Also known as
  • Kentroliet
  • Kentrolit

Where it forms, where it's found

Geological setting

Oxide zinc deposits.

Type locality
Chile
23recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Black · sometimes with dark red internal reflections
Streak
Brown to yellowish brown
Tenacity
brittle
Cleavage
Distinct/Good

(110)

Fracture
Irregular/Uneven
Density
6.26 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 88° · 2V calc = 88°
Refractive index
2.1 – 2.31
Surface relief
Very high
Principal indices
nα 2.1 · nβ 2.2 · nγ 2.31
Birefringence
0.21
Pleochroism
Strong

X= bright yellowish pink Y= reddish brown Z= deep brownish red

Dispersion
strong r < v
Extinction
Parallel
Michel-Lévy diagramhighlighted lineδ = 0.2100
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]2100 nm4th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation2100 nm
Order4th order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#62
Cell parameters
a = 6.961 Å · b = 11.018 Å · c = 9.964 Å
Ratio a:b:c
1 : 1.583 : 1.431
Morphology

Prismatic to equant. Isolated crystals or rosettes, sheaflike groups, massive.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead2207.200414.400
57.20%
8OOxygenOxygen915.999143.991
19.88%
25MnManganeseManganese254.938109.876
15.17%
14SiSiliconSilicon228.08556.170
7.75%
Total724.437100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ti
  • Al
  • Fe
  • Zn
  • Mg

Synonyms

  • Kentroliet
  • Kentrolit

In other languages

German
Kentrolith
Italian
Kentrolite

Classification

Strunz
10th ed.

9.BE.80

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BESi2O7 groups, with additional anions; cations in octahedral [6] and greater coordinationGroup
  • 9.BE.80KentroliteSpecies
Dana
8th ed.

56.02.10.02

  • 56Sorosilicates Si2o7 Groups, with Additional O, Oh, F and H2oClass
  • 56.02Si2O7 Groups and O, OH, F, and H2O with cations in [4] and/or >[4] coordinationType
  • 56.02.10Melanotekite groupGroup
  • 56.02.10.02KentroliteSpecies
CIM

14.13.7

  • 14Silicates not Containing AluminumClass
  • 14.13Silicates of PbGroup
  • 14.13.7KentroliteSpecies

Literature, links & citation

Citations
  1. 1880Damour, A., vom Rath, G. (1880) Ueber den Kentrolith, eine neue Mineralspecies. Zeitschrift für Krystallographie und Mineralogie, 5 (1). 32-35 doi:10.1524/zkri.1880.5.1.32DOI: 10.1524/zkri.1880.5.1.32
  2. 1891Flink, Gustaf (1891) Mineralogische Notizen III, 7. Kentrolith von Langbanshyttan. Meddelanden från Stockholms Högskola 115, Stockholms högskola. 14-20
  3. 1967Glasser, F. P. (1967) New data on kentrolite and melanotekite: ternary phase relations in the system PbO-Fe2O3-SiO2. American Mineralogist, 52 (7-8) 1085-1093
  4. 1979Gabelica-Robert, M., Tarte, P. (1979) Synthesis, X-ray diffraction and vibrational study of silicates and germanates isostructural with kentrolite Pb2Mn2Si2O9. Journal of Solid State Chemistry, 27. 179-190 doi:10.1016/0022-4596(79)90156-7DOI: 10.1016/0022-4596(79)90156-7
  5. 1991Moore, Paul Brian, Gupta, Pradip K. Sen, Shen, Jinchuan, Schlemper, Elmer O. (1991) The kentrolite-melanotekite series, 4Pb2(Mn,Fe)3+2O2[Si2O7]: Chemical crystallographic relations, lone-pair splitting, and cation relation to 8URe2. American Mineralogist, 76 (7-8) 1389-1399
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Kentrolite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/kentrolite-2185},
  note      = {Accessed 2026-05-11}
}