Kidwellite

NaFe3+9+x(PO4)6(OH)11 · 3H2O (x ≈ 0.33)
IMA status
  • Approved
IMA symbol
Kdw
IMA approved
1974
Also known as
  • IMA1974-024
  • Kidwelita
  • Kidwelliet

Where it forms, where it's found

Geological setting

Phosphate-bearing iron deposits

Rarely in phosphate-rich granite pegmatites

Type locality
Fodderstack Mountain
  1. Norman
  2. Montgomery County
  3. Arkansas
  4. USA

34.4041°, -93.7100°

56recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Greenish yellow · Greenish white · Yellow · Light green
Streak
yellow
Tenacity
brittle
Cleavage
Perfect

Perfect on (100)

Fracture
Splintery
Density
3.04 g/cm³

Optical

Optical type
Biaxial (-)
Refractive index
1.787 – 1.805
Surface relief
High
Principal indices
nα 1.787 · nβ 1.800 · nγ 1.805
Birefringence
0.018
Pleochroism
Non-pleochroic
Dispersion
extreme
UV response
Not fluorescent in UV
Michel-Lévy diagramhighlighted lineδ = 0.0180
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]180 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation180 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P2/c
Cell parameters
a = 20.117 Å · b = 5.185 Å · c = 13.978 Å
Cell angles
β = 107.07 °
Ratio a:b:c
1 : 0.258 : 0.695
Morphology

Usually acicular, but may rarely form almost rod-like crystals.

Type-locality form

Olive green botryoids or bands within other phosphate mineral botryoids.

Comment

Single-crystal data; slightly As-bearing.

Crystal structure

Synonyms

  • IMA1974-024
  • Kidwelita
  • Kidwelliet

In other languages

German
IMA 1974-024 · IMA1974-024 · Kidwellit
Spanish
Kidwellita
Italian
kidwellite
Russian
кидвелит · кидуелит

Classification

Strunz
10th ed.

8.DK.20

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DKWith large and medium-sized cations, (OH, etc.):RO4 > 1:1 and < 2:1Group
  • 8.DK.20KidwelliteSpecies
Dana
8th ed.

42.08.02.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.08(AB)5(XO4)3Zq·xH2OType
  • 42.08.02— unnamed intermediate level —Group
  • 42.08.02.01KidwelliteSpecies
CIM

19.14.2

  • 19PhosphatesClass
  • 19.14Phosphates of Fe and other metalsGroup
  • 19.14.2KidwelliteSpecies

Literature, links & citation

Citations
  1. 1978Moore, Paul B., Ito, Jun (1978) Kidwellite, NaFe93+(OH)10(PO4)6·5H2O, a new species. Mineralogical Magazine, 42 (321) 137-140 doi:10.1180/minmag.1978.042.321.21 DOI: 10.1180/minmag.1978.042.321.21
  2. 1979American Mineralogist (1979): 64: 242-243.
  3. 1980Braithwaite, R. S. W., Corke, Hilary (1980) Kidwellite from Cornwall. Mineralogical Magazine, 43 (331) 952-953 doi:10.1180/minmag.1980.043.331.25 DOI: 10.1180/minmag.1980.043.331.25
  4. 2004Kolitsch, U. (2004) The crystal structures of kidwellite and ‘laubmannite’, two complex fibrous iron phosphates. Mineralogical Magazine, 68 (1) 147-165 doi:10.1180/0026461046810177DOI: 10.1180/0026461046810177
  5. 2014Frost, Ray L., López, Andrés, Theiss, Frederick L., Scholz, Ricardo, Souza, Larissa (2014) The molecular structure of the phosphate mineral kidwellite NaFe3+9(PO4)6(OH)11⋅3H2O – A vibrational spectroscopic study. Journal of Molecular Structure, 1074. 429-434 doi:10.1016/j.molstruc.2014.06.055DOI: 10.1016/j.molstruc.2014.06.055
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Kidwellite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/kidwellite-2202},
  note      = {Accessed 2026-05-11}
}