Kihlmanite-(Ce)

Ce2TiO2(SiO4)(HCO3)2(H2O)
IMA status
  • Approved
IMA symbol
Kih-Ce
IMA approved
2012
Also known as
  • IMA2012-081
  • Kihlmaniet-(Ce)

Where it forms, where it's found

Geological setting

Intermediate zone of an arfvedsonite-aegirine-microcline vein in fenitized metavolcanic rock.

Type locality
Khibiny Station
  1. Kihlman Mountain
  2. Murmansk Oblast
  3. Russia

67.6731°, 33.2123°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Brown · reddish-brown

Yellowish-brown in transmitted light

Streak
Pale yellowish-brown
Tenacity
brittle
Cleavage
Perfect

on (010)

Fracture
Step-Like
Density
3.66 g/cm³

Optical

Optical type
Biaxial (+) · 2V calc = 89°
Refractive index
1.708 – 1.82
Surface relief
High
Principal indices
nα 1.708 · nβ 1.76 · nγ 1.82
Pleochroism
Non-pleochroic

not observed.

Dispersion
not observed
UV response
not observed
Michel-Lévy diagramhighlighted lineδ = 0.1120
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1120 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1120 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
P-1
Cell parameters
a = 4.994(2) Å · b = 7.54(2) Å · c = 15.48(4) Å
Cell angles
α = 103.5(4) ° · β = 90.7(2) ° · γ = 109.2(2) °
Ratio a:b:c
1 : 1.510 : 3.100
Morphology

Spherulites and sheaf-like aggregates of prismatic crystals, flattened on (010).

Parting
Perpendicular to c.
Type-locality form

Brown spherulites (up to 2 cm diameter) and sheaf-like aggregates of prismatic crystals, flattened on (010) and up to 0.5 mm diameter, in intimate association (intergrowths) with golden-green tundrite-(Ce).

Comment

From single-crystal X-ray diffraction data: a = 5.009(5), b = 7.533(5), c = 15.407(5) Å, α = 103.061(5), β = 91.006(5), γ = 109.285(5)°, V = 531.8(7) Å3, Z =2.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
58CeCeriumCerium2140.116280.232
47.32%
8OOxygenOxygen1315.999207.987
35.12%
22TiTitaniumTitanium147.86747.867
8.08%
14SiSiliconSilicon128.08528.085
4.74%
6CCarbonCarbon212.01124.022
4.06%
1HHydrogenHydrogen41.0084.032
0.68%
Total592.225100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • La
  • Nd
  • Nb
  • Na
  • Pr
  • Sm
  • (Al, Gd)

Synonyms

  • IMA2012-081
  • Kihlmaniet-(Ce)

In other languages

German
IMA 2012-081 · Kihlmanit-(Ce)
Italian
kihlmanite-(Ce)

Classification

Strunz
10th ed.

9.AH.60

  • 9SilicatesClass
  • 9.ANesosilicatesDivision
  • 9.AHNesosilicates with CO3, SO4, PO4, etc.Group
  • 9.AH.60Kihlmanite-(Ce)Species

Literature, links & citation

Citations
  1. 2013Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2013) IMA Commission on New Minerals, Nomenclature and Classification. CNMNC Newsletter No. 15. Mineralogical Magazine, 77 (1) 1-12 doi:10.1180/minmag.2013.077.1.01DOI: 10.1180/minmag.2013.077.1.01
  2. 2014Yakovenchuk, V. N., Krivovichev, S.V., Ivanyuk, G. Y., Pakhomovsky, Ya. A., Selivanova, E.A., Zhitova, E. A., Kalashnikova, G. O., Zolotarev, A. A., Mikhailova, J. A., Kadyrova, G. I. (2014) Kihlmanite-(Ce), Ce2TiO2[SiO4](HCO3)2(H2O), a new rare-earth mineral from the pegmatites of the Khibiny alkaline massif, Kola Peninsula, Russia. Mineralogical Magazine, 78 (3) 483-496 doi:10.1180/minmag.2014.078.3.01 DOI: 10.1180/minmag.2014.078.3.01
  3. 2016(2016) Kihlmanite-(Ce). Handbook of Mineralogy. Mineralogical Society of America
  4. 2017Panikorovskii T. L., Kalashnikova G. O., Zhitova E. S., Pakhomovsky Ya. A., Bocharov V. N., Yakovenchuk V. N., Zolotarev A. A. jr., Krivovichev S. V. (2017): Crystal chemistry of Na-rich kihlmanite-(Ce) from arfvedsonite-aegirine-microcline pegmatite at the Kihlman Mt. (Khibiny massif, Kola Peninsula, Russia). Zapiski RMO 146, 113-124.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Kihlmanite-(Ce) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/kihlmanite-ce-43601},
  note      = {Accessed 2026-05-11}
}