Killalaite

Ca6.4[H0.6Si2O7]2(OH)2
IMA status
  • Approved
IMA symbol
Kil
Discovered
1974
IMA approved
1973
Also known as
  • IMA1973-033
  • Killalaiet

Where it forms, where it's found

Geological setting

Thermally metamorphosed limestone

Type locality
Inishcrone
  1. Killala Bay
  2. Sligo County
  3. Connacht
  4. Ireland

54.2297°, -9.0922°

4recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Translucent
Colour
White · colorless in thin section
Cleavage
Perfect

Perfect on (100). Poor on (010) and (001).

Density
2.94 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 26° · 2V calc = 38°
Refractive index
1.634 – 1.648
Surface relief
Moderate
Principal indices
nα 1.634 – 1.635 · nβ 1.646 · nγ 1.642 – 1.648
Dispersion
r > v
Michel-Lévy diagramhighlighted lineδ = 0.0105
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]105 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation105 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/m
Cell parameters
a = 6.807 Å · b = 15.459 Å · c = 6.811 Å
Cell angles
β = 97.76 °
Ratio a:b:c
1 : 2.271 : 1.001
Z
4
Morphology

Elongated on [010]

Twinning

Complex penetration twinning, the composition plane of which includes [010].

Type-locality form

Well formed crystals to 2 mm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
20CaCalciumCalcium6.440.078256.499
40.84%
8OOxygenOxygen1615.999255.984
40.76%
14SiSiliconSilicon428.085112.340
17.89%
1HHydrogenHydrogen3.21.0083.226
0.51%
Total628.049100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1973-033
  • Killalaiet

In other languages

German
IMA 1973-033 · Killalait
Italian
Killalaite

Classification

Strunz
10th ed.

9.BE.85

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BESi2O7 groups, with additional anions; cations in octahedral [6] and greater coordinationGroup
  • 9.BE.85KillalaiteSpecies
Dana
8th ed.

56.02.09.02

  • 56Sorosilicates Si2o7 Groups, with Additional O, Oh, F and H2oClass
  • 56.02Si2O7 Groups and O, OH, F, and H2O with cations in [4] and/or >[4] coordinationType
  • 56.02.09Tilleyite - Killalaite groupGroup
  • 56.02.09.02KillalaiteSpecies
CIM

14.5.17

  • 14Silicates not Containing AluminumClass
  • 14.5Silicates of CaGroup
  • 14.5.17KillalaiteSpecies

Literature, links & citation

Citations
  1. 1974Fleischer, Michael (1974) New mineral names. American Mineralogist, 59 (11-12). 1330-1332
  2. 1974Nawaz, R. (1974) Killalaite, a new mineral from Co. Sligo, Ireland. Mineralogical Magazine, 39 (305) 544-548 doi:10.1180/minmag.1974.039.305.06 DOI: 10.1180/minmag.1974.039.305.06
  3. 1977Taylor, H. F. W. (1977) The crystal structure of killalaite. Mineralogical Magazine, 41 (319) 363-369 doi:10.1180/minmag.1977.041.319.08 DOI: 10.1180/minmag.1977.041.319.08
  4. 1977Nawaz, R. (1977) A second occurrence of killalaite. Mineralogical Magazine, 41 (320) 546-548 doi:10.1180/minmag.1977.041.320.25 DOI: 10.1180/minmag.1977.041.320.25
  5. 2001(2001) Killalaite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Killalaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/killalaite-2206},
  note      = {Accessed 2026-05-11}
}