Kingite

Al3(PO4)2F2(OH) · 7H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Kgi
Discovered
1956
Also known as
  • Kingiet

Where it forms, where it's found

Geological setting

Found in Cambrian and Upper Precambrian limestones. Probably of supergene origin. Thought to have been deposited by meteoric waters in fault zones and breccias during Tertiary times.

Type locality
Fairview Quarry
  1. Robertstown
  2. South Australia
  3. Australia

-33.8464°, 139.1261°

14recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Translucent
Colour
White · colorless · greenish yellow
Streak
White
Density
2.21 g/cm³

Optical

Optical type
Biaxial
Refractive index
1.514
Surface relief
Moderate
Principal indices
nβ 1.514
Dispersion
strong

Crystallography

Crystal system
Triclinic
Cell parameters
a = 9.15(1) Å · b = 10.00(1) Å · c = 7.24(2) Å
Cell angles
α = 98.6(1) ° · β = 93.6(1) ° · γ = 93.2(1) °
Ratio a:b:c
1 : 1.093 : 0.791
Z
2
Morphology

Platelets or irregular fragments, to 1 µm, aggregated in nodules; as crusts of intergrown spheroids resembling fish roe.

Type-locality form

White nodules to 5 cm in diameter.

Comment

Point Group: _1 or 1; Space Group: P_1 or P1.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1615.999255.984
56.63%
13AlAluminiumAluminium326.98280.946
17.91%
15PPhosphorusPhosphorus230.97461.948
13.71%
9FFluorineFluorine218.99837.996
8.41%
1HHydrogenHydrogen151.00815.120
3.34%
Total451.994100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Kingiet

In other languages

German
Kingit
Italian
kingite

Classification

Strunz
10th ed.

8.DC.47

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DCWith only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1Group
  • 8.DC.47KingiteSpecies
Dana
8th ed.

42.10.03.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.10A3(XO4)2Zq·xH2OType
  • 42.10.03— unnamed intermediate level —Group
  • 42.10.03.01KingiteSpecies
CIM

19.7.11

  • 19PhosphatesClass
  • 19.7Phosphates of Al aloneGroup
  • 19.7.11KingiteSpecies

Literature, links & citation

Citations
  1. 1957Fleischer, M. (1957) New mineral names. American Mineralogist, 42 (7-8) 580-586
  2. 1957Norrish, K.; Rogers, Lillian E. R.; Shapter, R. E. (1957) Kingite, a new hydrated aluminium phosphate mineral from Robertstown, South Australia. Mineralogical Magazine and Journal of the Mineralogical Society, 31 (236). 351-357 doi:10.1180/minmag.1957.031.236.01 DOI: 10.1180/minmag.1957.031.236.01
  3. 1970Kato, Toshio (1970) Cell dimensions of the hydrated phosphate, kingite. American Mineralogist, 55 (3-4). 515-517
  4. 2004Wallwork, K. S., Pring, A., Taylor, M. R., Hunter, B. A. (2004) The network of hydrogen bonding in kingite as revealed by a neutron-diffraction investigation of its deuterated analogue, Al3(PO4)2F3·7D2O. The Canadian Mineralogist, 42 (1) 135-141 doi:10.2113/gscanmin.42.1.135 DOI: 10.2113/gscanmin.42.1.135
  5. 2005(2005) Kingite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Kingite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/kingite-2210},
  note      = {Accessed 2026-05-11}
}