Kleemanite

ZnAl2(PO4)2(OH)2 · 3H2O
IMA status
  • Approved
IMA symbol
Klm
Discovered
1977
IMA approved
1978
Also known as
  • IMA1978-043
  • Kleemaniet

Where it forms, where it's found

Geological setting

weathering zone of manganiferous iron ore.

Type locality
Iron Monarch Main Pit
  1. Iron Knob
  2. Pastoral Unincorporated Area
  3. South Australia
  4. Australia

-32.7447°, 137.1395°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
colorless to pale brownish yellow
Density
2.84 g/cm³

Optical

Optical type
Biaxial
Refractive index
1.598 – 1.614
Surface relief
Moderate
Principal indices
nα 1.598 · nγ 1.614
Dispersion
r < v weak
Michel-Lévy diagramhighlighted lineδ = 0.0160
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]160 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation160 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 7.282(8) Å · b = 7.190(5) Å · c = 9.770(8) Å
Cell angles
β = 110.2 °
Ratio a:b:c
1 : 0.987 : 1.342
Z
2
Morphology

matted coatings of very fine-bladed acicular crystals

Twinning

Multiple twinning parallel to fiber elongation probable.

Type-locality form

Ochreous in appearance, but under a hand lens it is composed of a very fine, hair-like mass of crystals.

Comment

Point Group: 2/m or 2; Space Group: P2/m, P21/m, P2, or P21.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1315.999207.987
52.35%
30ZnZincZinc165.38065.380
16.45%
15PPhosphorusPhosphorus230.97461.948
15.59%
13AlAluminiumAluminium226.98253.964
13.58%
1HHydrogenHydrogen81.0088.064
2.03%
Total397.343100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1978-043
  • Kleemaniet

In other languages

German
IMA 1978-043 · Kleemanit
Italian
Kleemanite

Classification

Strunz
10th ed.

8.DC.17

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DCWith only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1Group
  • 8.DC.17KleemaniteSpecies
Dana
8th ed.

42.11.12.02

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.11(AB)3(XO4)2Zq·xH2OType
  • 42.11.12Gatumbaite GroupGroup
  • 42.11.12.02KleemaniteSpecies
CIM

19.8.22

  • 19PhosphatesClass
  • 19.8Phosphates of Al and other metalsGroup
  • 19.8.22KleemaniteSpecies

Literature, links & citation

Citations
  1. 1979Fleischer, Michael, Burns, Roger G., Cabri, Louis J., Chao, George Y., Hogarth, D. D., Pabst, Adolf (1979) New Mineral Names. American Mineralogist, 64 (11-12) 1329-1334
  2. 1979Pilkington, E. S., Segnit, E. R., Watts, J., Francis, G. (1979) Kleemanite, a new zinc aluminium phosphate. Mineralogical Magazine, 43 (325) 93-95 doi:10.1180/minmag.1979.043.325.03 DOI: 10.1180/minmag.1979.043.325.03
  3. 1993Lai, L. and Sun, Y. (1993) Discovery of kleemanite, a zinc aluminum phosphate in China. Yanshi Kuangwuxue Zazhi: 12: 279-283 (in Chinese with English summary).
  4. 2005(2005) Kleemanite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Kleemanite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/kleemanite-2224},
  note      = {Accessed 2026-05-11}
}