Knasibfite

K3Na4(SiF6)3(BF4)
IMA status
  • Approved
IMA symbol
Ksf
IMA approved
2006
Also known as
  • IMA2006-042
  • Knasibfiet

Where it forms, where it's found

Type locality
La Fossa crater
  1. Vulcano Island
  2. Lipari
  3. Eolie Islands (Aeolian Islands)
  4. Metropolitan City of Messina
  5. Sicily
  6. Italy

38.4034°, 14.9614°

1recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
Colourless
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
None observed
Density
2.75 g/cm³

Optical

Optical type
Isotropic
Refractive index
1.32
Surface relief
Low
Principal indices
nα 1.32
UV response
Not fluorescent

Crystallography

Crystal system
Orthorhombic
Space group
#27
Cell parameters
a = 5.522 Å · b = 17.106 Å · c = 9.175 Å
Ratio a:b:c
1 : 3.098 : 1.662
Unit cell volume
866.7 ų
Z
2
Morphology

(001), (100), (010), (110), (011) and (101)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
9FFluorineFluorine2218.998417.956
57.87%
19KPotassiumPotassium339.098117.294
16.24%
11NaSodiumSodium422.99091.960
12.73%
14SiSiliconSilicon328.08584.255
11.66%
5BBoronBoron110.81010.810
1.50%
Total722.275100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2006-042
  • Knasibfiet

In other languages

German
IMA 2006-042 · Knasibfit
Italian
knasibfite

Classification

Strunz
10th ed.

3.CH.25

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.CHSilicofluoridesGroup
  • 3.CH.25KnasibfiteSpecies

Literature, links & citation

Citations
  1. 2008Demartin, F., Gramaccioli, C. M., Campostrini, I., Orlandi, P. (2008) Knasibfite, K3Na4[SiF6]3[BF4], a new hexafluorosilicate-tetrafluoroborate from La Fossa Crater, Vulcano, Aeolian Islands, Italy. The Canadian Mineralogist, 46 (2) 447-453 doi:10.3749/canmin.46.2.447 DOI: 10.3749/canmin.46.2.447
  2. 2011(2011) Knasibfite. Handbook of Mineralogy. Mineralogical Society of America
  3. 2020Bandemehr, J., Josefin, K., Sergei, I., Malte, S., Florian, K. (2020) Laboratory synthesis and characterization of Knasibfite K3Na4[SiF6]3[BF4] and the homologous Ge compound K3Na4[GeF6]3[BF4]. Zeitschrift für Kristallographie - Crystalline Materials.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Knasibfite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/knasibfite-31406},
  note      = {Accessed 2026-05-11}
}