Kogarkoite

Na3(SO4)F
IMA status
  • Approved
IMA symbol
Kog
Discovered
1973
Also known as
  • IMA1970-038

Where it forms, where it's found

Geological setting

In nepheline syenite pegmatite (at Lovozero).

Type locality
Alluaiv Mountain
  1. Lovozersky District
  2. Murmansk Oblast
  3. Russia

67.8645°, 34.5124°

15recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
White · pale blue · pale pink
Streak
White
Density
2.66 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = Nearly 0°
Refractive index
1.439 – 1.442
Surface relief
Low
Principal indices
nα 1.439 · nβ 1.439 · nγ 1.442
Birefringence
0.0029(3), determined by Berek compensator on two synthetic crystals, 0.36 and 0.33 mm thick.
Pleochroism
Weak
Dispersion
dispersion not observed
UV response
Fluoresces cream to pale blue under SW UV and green under LW UV.
Notes

Very nearly uniaxial

Michel-Lévy diagramhighlighted lineδ = 0.0029
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]29 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation29 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/m
Cell parameters
a = 18.079(2) Å · b = 6.958(1) Å · c = 11.443(2) Å
Cell angles
β = 107.71 °
Ratio a:b:c
1 : 0.385 : 0.633
Unit cell volume
1371.24 ų
Z
12
Twinning

Common, by rotation about [102] (or pseudohexagonal [0001]), giving intergrown and contact trillings.

Type-locality form

Pale blue grains and aggregates occupying interstices between nepheline and feldspar.

Comment

Cell parameters from Fanfani et al. (1980). Note that a=18.074 in abstract but 18.079 in body.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
11NaSodiumSodium322.99068.970
37.48%
8OOxygenOxygen415.99963.996
34.78%
16SSulfurSulfur132.06032.060
17.42%
9FFluorineFluorine118.99818.998
10.32%
Total184.024100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1970-038

In other languages

German
IMA 1970-038 · Kogarkoit
Spanish
Kogarkoíta
Italian
Kogarkoite
Russian
Когаркоит

Classification

Strunz
10th ed.

7.BD.15

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BDWith only large cationsGroup
  • 7.BD.15KogarkoiteSpecies
Dana
8th ed.

30.01.06.01

  • 30Anhydrous Sulfates Containing Hydroxyl or HalogenClass
  • 30.01(AB)m(XO4)pZq, where m:p>2:1Type
  • 30.01.06— unnamed intermediate level —Group
  • 30.01.06.01KogarkoiteSpecies
CIM

26.1

  • 26Sulphates with HalideClass
  • 26.1— unnamed intermediate level —Group
  • 26.1KogarkoiteSpecies

Literature, links & citation

Citations
  1. 1859de Marignac, Ch. (1859) Recherches sur les formes cristallines et la composition chimique de divers sels. Annales des Mines: 15: 221-290.
  2. 1961Kogarko, L.N. (1961) Chlorine-free schairerite from the nepheline syenites of the Lovozero massif (Kola Peninsula). Doklady Akademii Nauk SSSR: 139: 435437. (in Russian) (trans. Doklady Earth Sciences Sec. 1: 39: 839-841 (January, 1963) 1).
  3. 1963Pabst, A., Sawyer, D. L., Switzer, George (1963) Galeite and related phases in the system Na2SO4-NaF-NaCl. American Mineralogist, 48 (5-6) 485-510
  4. 1973Pabst, Adolf, Sharp, and William N. (1973) Kogarkoite, a new natural phase in the system Na2SO4-NaF-NaCl. American Mineralogist, 58 (1-2) 116-127
  5. 1980Fanfani, L., Giuseppetti, G., Tadini, C., Zanazzi, P. F. (1980) The crystal structure of kogarkoite, Na3SO4F. Mineralogical Magazine, 43 (330) 753-759 doi:10.1180/minmag.1980.043.330.08 DOI: 10.1180/minmag.1980.043.330.08
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Kogarkoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/kogarkoite-2236},
  note      = {Accessed 2026-05-11}
}