Kozyrevskite

Cu4O(AsO4)2
IMA status
  • Approved
IMA symbol
Kzy
IMA approved
2013
Also known as
  • IMA2013-023
  • Kozyrevskiet

Where it forms, where it's found

Geological setting

Fumarole. The temperature measured at the collecting site was 360-380ºC.

Type locality
Arsenatnaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.6833°, 160.2333°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Bright grass green to light yellowish green
Tenacity
brittle
Cleavage
Perfect

(100) and (001) perfect

Fracture
Step-Like
Density
4.934 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 75° · 2V calc = 70°
Refractive index
1.885 – 1.9
Surface relief
Very high
Principal indices
nα 1.885 · nβ 1.895 · nγ 1.900
Pleochroism
Visible

Distinct, X = green; Y = Z = yellowish green.

Dispersion
r > v, strong.
Extinction
Extinction is straight, elongation is negative. Orientation is X = b.
Notes

Absorption X > Y = Z.

Michel-Lévy diagramhighlighted lineδ = 0.0150
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]150 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation150 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#71
Cell parameters
a = 8.2581(4) Å · b = 6.4026(4) Å · c = 13.8047(12) Å
Ratio a:b:c
1 : 0.775 : 1.672
Unit cell volume
729.9 ų
Z
4
Morphology

Prismatic crystals up to 0.3 mm long in clusters and as individual crystals.

Type-locality form

Prismatic crystals up to 0.3 mm long in clusters and as individual crystals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper463.546254.184
46.38%
33AsArsenicArsenic274.922149.844
27.34%
8OOxygenOxygen915.999143.991
26.28%
Total548.019100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2013-023
  • Kozyrevskiet

In other languages

German
IMA 2013-023 · Kozyrevskit
Italian
kozyrevskite

Classification

Strunz
10th ed.

8.BB.52b

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BBWith only medium-sized cations, (OH, etc.):RO4 about 1:1Group
  • 8.BB.52bKozyrevskiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1995Adams, Richard D., Layland, Ralph, Payen, Christophe (1995) Cu4(AsO4)2(O): A New Copper Arsenate with Unusual Low Temperature Magnetic Properties. Inorganic Chemistry, 34 (22) 5397-5398 doi:10.1021/ic00126a002DOI: 10.1021/ic00126a002
  2. 2013Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2013) New minerals and nomenclature modifications approved in 2013. CNMNC Newsletter No 16. Mineralogical Magazine, 77 (6) 2695-2709 doi:10.1180/minmag.2013.077.6.01DOI: 10.1180/minmag.2013.077.6.01
  3. 2014Pekov, I. V., Zubkova, N. V., Yapaskurt, V. O., Belakovskiy, D. I., Vigasina, M. F., Sidorov, E. G., Pushcharovsky, D. Yu. (2014) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. II. Ericlaxmanite and kozyrevskite, two natural modifications of Cu4O(AsO4)2. Mineralogical Magazine, 78 (7) 1553-1569 doi:10.1180/minmag.2014.078.7.03 DOI: 10.1180/minmag.2014.078.7.03
  4. 2016(2016) Kozyrevskite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Kozyrevskite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/kozyrevskite-43955},
  note      = {Accessed 2026-05-11}
}