Krotite

CaAl2O4
IMA status
  • Approved
IMA symbol
Kro
IMA approved
2010
Also known as
  • IMA2010-038
  • Krotiet

Where it forms, where it's found

Geological setting

An unusual Ca-,Al-rich refractory inclusion in a carbonaceous chondrite meteorite. A low-pressure CaAl2O4 mineral, likely formed by condensation or crystallization from a melt in the solar nebula.

Type locality
Northwest Africa 1934 meteorite (NWA 1934)
  1. Northwest Africa Meteorites
2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789106.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless
Streak
White
Tenacity
brittle
Cleavage
Distinct/Good

Good on (100) and (010).

Fracture
Conchoidal
Density
2.944 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 54.4° · 2V calc = 55.6°
Refractive index
1.608 – 1.635
Surface relief
Moderate
Principal indices
nα 1.608 · nβ 1.629 · nγ 1.635
Pleochroism
Weak

Colorless to very pale gray.

Dispersion
None observed.
Extinction
X = b; Y ≈ a; Z ≈ c.
UV response
Not fluorescent.
Notes

Absorption: X > Y = Z (barely noticeable).

Michel-Lévy diagramhighlighted lineδ = 0.0270
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]270 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation270 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 8.6996(3) Å · b = 8.0994(3) Å · c = 15.2170(11) Å
Cell angles
β = 90.188(6) °
Ratio a:b:c
1 : 0.931 : 1.749
Morphology

No crystal forms observed in type material.

Twinning

None observed.

Type-locality form

Aggregates with the individual crystals ranging from 10 to 350 μm in size.

Comment

Space group P21/n.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
40.49%
13AlAluminiumAluminium226.98253.964
34.15%
20CaCalciumCalcium140.07840.078
25.36%
Total158.038100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2010-038
  • Krotiet

In other languages

German
IMA 2010-038 · Krotit
Spanish
Krotita · Óxido de calcio-aluminio
Russian
Кротит

Classification

Strunz
10th ed.

4.BC.35

  • 4OxidesClass
  • 4.BMetal: Oxygen = 3:4 and similarDivision
  • 4.BCWith medium-sized and large cationsGroup
  • 4.BC.35KrotiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1976Hörkner, W., Müller-Buschbaum, Hk. (1976) Zur kristallstruktur von CaAl2O4. Journal of Inorganic and Nuclear Chemistry, 38 (5) 983-984 doi:10.1016/0022-1902(76)80011-5DOI: 10.1016/0022-1902(76)80011-5
  2. 2001Kahlenberg, Volker (2001) On the Al/Fe substitution in iron doped monocalcium aluminate - the crystal structure of CaAl1.8Fe0.2O4. European Journal of Mineralogy, 13 (2) 403-410 doi:10.1127/0935-1221/01/0013-0403DOI: 10.1127/0935-1221/01/0013-0403
  3. 2010Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2010) New minerals and nomenclature modifications approved in 2010, CNMNC Newsletter No 5. Mineralogical Magazine, 74 (5) 859-862 doi:10.1180/s0026461x00056887 DOI: 10.1180/s0026461x00056887
  4. 2011Ma, C., Kampf, A. R., Connolly, H. C., Beckett, J. R., Rossman, G. R., Smith, S. A. S., Schrader, D. L. (2011) Krotite, CaAl2O4, a new refractory mineral from the NWA 1934 meteorite. American Mineralogist, 96 (5) 709-715 doi:10.2138/am.2011.3693DOI: 10.2138/am.2011.3693
  5. 2021(2021) Krotite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Krotite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/krotite-40468},
  note      = {Accessed 2026-05-11}
}