Lapeyreite

Cu3O[AsO3(OH)]2 · H2O
IMA status
  • Approved
IMA symbol
Lpy
IMA approved
2008
Also known as
  • IMA2003-023b
  • Lapeyreiet

Where it forms, where it's found

Geological setting

The cupriferous ore occurs in two distinct zones 400 m apart: a northern and a southern zone situated, respectively, in the districts of Guillaume and Daluis.

Type locality
Roua Mines (Clue de Roua)
  1. Daluis
  2. Nice Arrondissement
  3. Alpes-Maritimes
  4. Provence-Alpes-Côte d'Azur
  5. France

44.0304°, 6.8677°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Transparent · Translucent
Colour
Dark pistachio-green
Streak
Yellowish green
Tenacity
brittle
Cleavage
Perfect

Perfect cleavage on (001), and good cleavage on (100).

Fracture
Conchoidal
Density
4.385 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 76° · 2V calc = 77°
Refractive index
1.82 – 1.9
Surface relief
Very high
Principal indices
nα 1.82 · nβ 1.85 · nγ 1.90
Pleochroism
Strong

X = light yellow-green, Y = pistachio-green, Z = dark pistachio-green

Dispersion
r > v, medium
UV response
none
Notes

X ^ c ~ 12°, Y = a, Z = b

Michel-Lévy diagramhighlighted lineδ = 0.0800
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]800 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation800 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 19.158(3) Å · b = 2.9361(6) Å · c = 9.193(2) Å
Cell angles
β = 103.26 °
Ratio a:b:c
1 : 0.153 : 0.480
Z
8
Morphology

Forms: (100), (010), and (001). Aggregates of elongate rectangular crystals (parallel to [010], flattened on (001)); acicular fibrous Crystals; powdery masses.

Twinning

In the type specimen, all crystals are twinned on the (001) plane. Only observed with X-rays, not binocular microscope or macroscopically.

Type-locality form

As aggregates in geodes of cuprite (0.5 mm diameter), invariably in intimate association with trippkeite.

Comment

Z = 8/3.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper363.546190.638
37.79%
8OOxygenOxygen1015.999159.990
31.71%
33AsArsenicArsenic274.922149.844
29.70%
1HHydrogenHydrogen41.0084.032
0.80%
Total504.504100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2003-023b
  • Lapeyreiet

In other languages

German
IMA 2003-023b · Lapeyreit
Italian
lapeyreite

Classification

Strunz
10th ed.

8.DB.47

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DBWith only medium-sized cations, (OH, etc.):RO4< 1:1Group
  • 8.DB.47LapeyreiteSpecies

Literature, links & citation

Citations
  1. 2000Sarp, H., Mari, G., Mari, D., Rolland, P., Lapeyre, L. (2000): Gilmarite, rollandite, théoparacelsite, radovanite, nouvelles espèces minérales de Roua (Daluis de Guillaumes, Alpes-Maritimes, France). Riviéra Scientifique, 84, 19-24.
  2. 2008Williams, P.A., Hatert, F., Pasero, M. (2008) New minerals approved in 2008. in International Mineralogical Association: 1-13.
  3. 2010Sarp, H., Černy, R., Babalik, H., Hatipoğlu, M., Mari, G. (2010) Lapeyreite, Cu3O[AsO3(OH)]2.0.75H2O, a new mineral: Its description and crystal structure. American Mineralogist, 95 (1) 171-176 doi:10.2138/am.2010.3225 DOI: 10.2138/am.2010.3225
  4. 2021(2021) Lapeyreite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Lapeyreite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/lapeyreite-38830},
  note      = {Accessed 2026-05-11}
}