Larderellite

(NH4)B5O7(OH)2 · H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ldr
Discovered
1854
Also known as
  • Borate de Chaux
  • Larderelliet

Where it forms, where it's found

Geological setting

Boric acid fumaroles in a volcanic region.

Type locality
Larderello
  1. Pomarance
  2. Pisa Province
  3. Tuscany
  4. Italy

43.2333°, 10.8667°

2recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Translucent
Colour
White · yellowish due to impurities · colourless in transmitted light
Streak
White
Cleavage
Perfect

On (001) (?) and (010) (?).

Density
1.905 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 58° · 2V calc = 56°
Refractive index
1.493 – 1.561
Surface relief
Moderate
Principal indices
nα 1.493 · nβ 1.509 · nγ 1.561
Dispersion
none
Michel-Lévy diagramhighlighted lineδ = 0.0680
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]680 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation680 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/a
Cell parameters
a = 11.64(1) Å · b = 7.62(1) Å · c = 9.45(1) Å
Cell angles
β = 96.75 °
Ratio a:b:c
1 : 0.655 : 0.812
Z
4
Morphology

Microscopic rhomboidal tablets flattened (100). The acute plane angle of the rhombs is ~ 68°.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1015.999159.990
67.76%
5BBoronBoron510.81054.050
22.89%
7NNitrogenNitrogen114.00714.007
5.93%
1HHydrogenHydrogen81.0088.064
3.42%
Total236.111100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Borate de Chaux
  • Larderelliet

In other languages

German
Larderellit
Italian
Larderellite

Classification

Strunz
10th ed.

6.EB.05

  • 6BoratesClass
  • 6.EPentaboratesDivision
  • 6.EBIno-pentaboratesGroup
  • 6.EB.05LarderelliteSpecies
Dana
8th ed.

26.05.04.01

  • 26Hydrated Borates Containing Hydroxyl or HalogenClass
  • 26.05PentaboratesType
  • 26.05.04— unnamed intermediate level —Group
  • 26.05.04.01LarderelliteSpecies
CIM

9.1.14

  • 9BoratesClass
  • 9.1Borates of the alkalis and boric acidGroup
  • 9.1.14LarderelliteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1806Mascagni (1806) Viagg. Tosc.: 3.
  2. 1832Beudant, François-Sulpice (1832) Traité élémentaire de minéralogie. Deuxiéme Edition [Elementary Treatise on Mineralogy. Second Edition] (2nd ed.) Vol. 2 - Tome II [Volume II]. Chez Verdière.
  3. 1844Alger-Phillips (1844): 318 (as Borocalcite).
  4. 1854Bechi, E. (1854) Analysis of several native borates: larderellite, (new species). American Journal of Science: 67: 129-130.
  5. 1863Forbes, D. (1863) On the chemical composition of some Chilian minerals. Philosophical Magazine and Journal of Science: 25: 103-114. (as Hayesine, pg 113)
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Larderellite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/larderellite-2332},
  note      = {Accessed 2026-05-11}
}