Lehmannite

Na18Cu12TiO8(AsO4)8FCl5
IMA status
  • Approved
IMA symbol
Leh
IMA approved
2018
Also known as
  • IMA2017-057a
  • Lehmanniet

Where it forms, where it's found

Geological setting

Volcanic fumarole.

Volcanic fumarole

Type locality
Arsenatnaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.6833°, 160.2333°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent · Opaque
Colour
Dark greyish green to olive-greenish black

Translucent only in thin sections.

Streak
Greyish green with an olive hue.
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
3.676 g/cm³

Optical

Pleochroism
Not Visible
Optical colour
Dark grey.
Anisotropism
Very weak.
Bireflectance
Very weak.
Internal reflections
Weak, brown.
Tropism
Anisotropic
Reflectance R%
(8.3,8.9) 400, (8.2,8.9) 420, (8.2,8.8) 440, (8.1,8.7) 460, (8.1,8.7) 470, (8.1,8.7) 480, (8.0,8.7) 500, (8.0,8.6) 520, (7.9,8.6) 540, (7.9,8.5) 546, (7.9,8.5) 560, (7.8,8.5) 580, (7.6,8.4) 589, (7.7,8.4) 600, (7.7,8.4) 620, (7.6,8.3) 640, (7.6,8.3) 650, (7.6,8.3) 660, (7.5,8.2) 680, (7.5,8.1) 700
Reflected-light panel
7.9 %anisotropic · dual curve
Specimen sRGB 106, 73, 38
White reference100 % reflector under same lamp
R₁ R₂
Mode
Bireflectance
Very weak.
Anisotropism
Very weak.
Reflected colour
Dark grey.
Internal reflections
Weak, brown.

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 10.824(1) Å · b = 21.108(2) Å · c = 11.856(1) Å
Cell angles
β = 117.195(8) °
Ratio a:b:c
1 : 1.950 : 1.095
Unit cell volume
2409.2 ų
Morphology

Individual crystals are equant, thick tabular or short prismatic, with pyramid-like terminations.

Twinning

Cyclic interpenetration twins, similar to phillipsite.

Parting
None observed.
Type-locality form

Equant crystals, up to 20 × 20 × 30 sq. μm, usually intergrown to form thin crusts, up to 2 × 3 cm in area.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper1263.546762.552
28.67%
8OOxygenOxygen4015.999639.960
24.06%
33AsArsenicArsenic874.922599.376
22.54%
11NaSodiumSodium1822.990413.820
15.56%
17ClChlorineChlorine535.450177.250
6.66%
22TiTitaniumTitanium147.86747.867
1.80%
9FFluorineFluorine118.99818.998
0.71%
Total2659.823100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2017-057a
  • Lehmanniet

In other languages

German
IMA 2017-057a · Lehmannit

Classification

Strunz
10th ed.

8.BK.35

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BKWith medium-sized and large cations, (OH, etc.):RO4 = 2:1, 2.5:1Group
  • 8.BK.35LehmanniteSpecies

Literature, links & citation

Citations
  1. 2018Hålenius, Ulf, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2018) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) NEWSLETTER 46. European Journal of Mineralogy, 30 (6) 1181-1189 doi:10.1127/ejm/2018/0030-2819DOI: 10.1127/ejm/2018/0030-2819
  2. 2020Pekov, I.V., Britvin, S.N., Yapaskurt, V.O., Koshlyakova, N.N., Polekhovsky, Yu.S., Göttlicher, J., Chukanov, N.V., Vigasina, M.F., Krivovichev, S.V., Turhkova, A.G., Sidorov, E.G. (2020) Arsmirandite, Na18Cu12Fe3+O8(AsO4)8Cl5, and lehmannite, Na18Cu12TiO8(AsO4)8FCl5, new minerals from fumerole exhalations of the Tolbachik Volcano, Kamchatka, Russia. Zapiski RMO, 149. 1-17
  3. 2020Britvin, S. N., Pekov, I. V., Yapaskurt, V. O., Koshlyakova, N. N., Göttlicher, J., Krivovichev, S. V., Turchkova, A. G., Sidorov, E. G. (2020). Polyoxometalate chemistry at volcanoes: discovery of a novel class of polyoxocuprate nanoclusters in fumarolic minerals. Scientific Reports: 10(1): 1-7.
  4. 2022(2022) Lehmannite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Lehmannite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/lehmannite-53217},
  note      = {Accessed 2026-05-11}
}