Leightonite

K2Ca2Cu(SO4)4 · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Lgh
Discovered
1938
Also known as
  • Leightoniet

Where it forms, where it's found

Type locality
Chuquicamata Mine
  1. Chuquicamata District
  2. Calama
  3. El Loa Province
  4. Antofagasta
  5. Chile

-22.2894°, -68.9011°

8recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Pale blue · greenish-blue · pale blue in transmitted light.
Cleavage
None Observed
Density
2.95 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 60° · 2V calc = 86°
Refractive index
1.574 – 1.595
Surface relief
Moderate
Principal indices
nα 1.574 – 1.578 · nβ 1.587 · nγ 1.595
Dispersion
very weak
Michel-Lévy diagramhighlighted lineδ = 0.0190
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]190 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation190 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 11.654(2) Å · b = 7.497(1) Å · c = 10.097(1) Å
Cell angles
β = 125.21(1) °
Ratio a:b:c
1 : 0.643 : 0.866
Z
2
Morphology

Pseudo-orthorhombic. Blades or laths elongated [001] and flattened (100); rarely equant. Curved surfaces cutting away more or less of the front edges of the prism produce an hour-glass appearance. Also occurs as cross-fiber veinlets.

Twinning

Repeated lamellar twinning on (100) and (010) of a sub-rectangular triclinic structure results in mimetic orthorhombic symmetry.

Type-locality form

cross-fiber veinlet fillings and crystals in open cavities.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1815.999287.982
44.85%
16SSulfurSulfur432.060128.240
19.97%
20CaCalciumCalcium240.07880.156
12.48%
19KPotassiumPotassium239.09878.196
12.18%
29CuCopperCopper163.54663.546
9.89%
1HHydrogenHydrogen41.0084.032
0.63%
Total642.152100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Leightoniet

In other languages

German
Leightonit
Spanish
Leightonita
Italian
Leightonite

Classification

Strunz
10th ed.

7.CC.70

  • 7SulfatesClass
  • 7.CSulfates (selenates, etc.) without additional anions, with H2ODivision
  • 7.CCWith medium-sized and large cationsGroup
  • 7.CC.70LeightoniteSpecies
Dana
8th ed.

29.04.05.02

  • 29Hydrated Acid and Normal SulfatesClass
  • 29.04AmBn(XO4)p·xH2O, with (m+n):p < 3:2 and > 1:1Type
  • 29.04.05— unnamed intermediate level —Group
  • 29.04.05.02LeightoniteSpecies
CIM

25.2.18

  • 25SulphatesClass
  • 25.2Sulphates of Cu and AgGroup
  • 25.2.18LeightoniteSpecies

Literature, links & citation

Citations
  1. 1938Palache, Charles (1938) Leightonite, a new sulphate of copper from Chile. American Mineralogist, 23 (1) 34-37
  2. 1938Peacock, M. A. (1938) The relation of leightonite to polyhalite. American Mineralogist, 23 (1) 38-45
  3. 1938Bandy, Mark C. (1938) Mineralogy of three sulphate deposits of northern Chile. American Mineralogist, 23 (11) 669-760
  4. 1962Loan, Paul R. Van (1962) An x-ray study of leightonite. The Canadian Mineralogist, 7 (2). 272-277
  5. 2002Menchetti, Silvio, Bindi, Luca, Bonazzi, Paola, Olmi, Filippo (2002) Disordered distribution of Cu in the crystal structure of leightonite, K2Ca2Cu(SO4)4·2H2O. American Mineralogist, 87 (5) 721-725 doi:10.2138/am-2002-5-615 DOI: 10.2138/am-2002-5-615
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Leightonite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/leightonite-2369},
  note      = {Accessed 2026-05-11}
}