Lemanskiite

NaCaCu5(AsO4)4Cl · 3H2O
IMA status
  • Approved
IMA symbol
Lmk
Discovered
1998
IMA approved
1999
Also known as
  • Chetlemanskiite
  • IMA1999-037
  • Lemanskiiet

Where it forms, where it's found

Geological setting

Occurs in the oxidized zone of an enargite-rich gold deposit in an arid environment.

Type locality
Guanaco Mine
  1. Taltal
  2. Antofagasta Province
  3. Antofagasta
  4. Chile

-25.1023°, -69.5373°

8recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Sky blue
Streak
Sky blue
Cleavage
Perfect

(001)

Fracture
Irregular/Uneven
Density
3.78 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.647 – 1.749
Surface relief
High
Principal indices
nω 1.749 · nε 1.647
Pleochroism
Strong

O dark green-blue, E light blue-green

UV response
None
Michel-Lévy diagramhighlighted lineδ = 0.1020
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1020 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1020 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#15
Cell parameters
a = 9.250(2) Å · b = 10.0058(10) Å · c = 10.412(17) Å
Cell angles
β = 97.37 °
Ratio a:b:c
1 : 1.082 : 1.126
Unit cell volume
921.7 ų
Z
2
Morphology

Thin tetragonal plates. Crystals bent to the angstrom level. Cell data and system have been updated with information provided in Dubrovka and al. (2018).

Twinning

None mentioned.

Parting
None.
Type-locality form

Rosette-shaped aggregates of thin platey crystals.

Comment

Originally (Ondruš et al., 2006) assumed to be tetragonal (space group P4122 or P4322), with a 9.9758(4), c 36.714(1) Å, V 3653.6(2) Å3.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper563.546317.730
30.97%
8OOxygenOxygen1915.999303.981
29.63%
33AsArsenicArsenic474.922299.688
29.21%
20CaCalciumCalcium140.07840.078
3.91%
17ClChlorineChlorine135.45035.450
3.45%
11NaSodiumSodium122.99022.990
2.24%
1HHydrogenHydrogen61.0086.048
0.59%
Total1025.965100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Chetlemanskiite
  • IMA1999-037
  • Lemanskiiet

In other languages

German
IMA 1999-037 · Lemanskiit
Italian
Lemanskiite

Classification

Strunz
10th ed.

8.DG.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DGWith large and medium-sized cations, (OH, etc.):RO4< 0.5:1Group
  • 8.DG.05LemanskiiteSpecies

Literature, links & citation

Citations
  1. 2006Ondruš, P., Veselovský, F., Skála, R., Sejkora, J., Pažout, R., Fryda, J., Gabašová, A., Vajdak, J. (2006) Lemanskiite, NaCaCu5(AsO4)4Cl·5H2O, a new mineral species from the Abundancia mine, Chile. The Canadian Mineralogist, 44 (2) 523-531 doi:10.2113/gscanmin.44.2.523 DOI: 10.2113/gscanmin.44.2.523
  2. 2007Giester, Gerald; Kolitsch, Uwe; Leverett, Peter; Turner, Peter; Williams, Peter A. (2007) The crystal structures of lavendulan, sampleite, and a new polymorph of sampleite. European Journal of Mineralogy, 19 (1). 75-93 doi:10.1127/0935-1221/2007/0019-0075DOI: 10.1127/0935-1221/2007/0019-0075
  3. 2015(2015) Lemanskiite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2018Zubkova, N. V., Pekov, I. V., Chukanov, N. V., Kasatkin, A. V., Ksenofontov, D. A., Yapaskurt, V. O., Britvin, S. N., Pushcharovsky, D. Yu. (2018) Redefinition of Lemanskiite: New Mineralogical Data, Crystal Structure, and Revised Formula NaCaCu5(AsO4)4Cl · 3H2O. Geology of Ore Deposits, 60 (7) 594-606 doi:10.1134/s1075701518070115DOI: 10.1134/s1075701518070115
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Lemanskiite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/lemanskiite-9658},
  note      = {Accessed 2026-05-11}
}