Leogangite

Cu10(AsO4)4(SO4)(OH)6 · 8H2O
IMA status
  • Approved
IMA symbol
Lgg
IMA approved
1998
Also known as
  • IMA1998-032
  • Leogangiet

Where it forms, where it's found

Geological setting

Alteration product of arsenic-rich fahlore in vugs of a tennantite-bearing dolomite breccia, intergrown with olivenite and malachite.

Type locality
Magnesite mine
  1. Inschlag Alp
  2. Schwarzleograben
  3. Hütten
  4. Leogang
  5. Zell am See District
  6. Salzburg
  7. Austria

47.4261°, 12.6647°

16recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Transparent
Colour
Green with a bluish tint
Streak
Light green
Cleavage
Perfect

parallel to (100)

Density
3.55 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 182°
Refractive index
1.59 – 1.74
Surface relief
High
Principal indices
nω 1.59 · nε 1.74 · n 1.744
Pleochroism

Blue-green to pale green.

Michel-Lévy diagramhighlighted lineδ = 0.1500
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1500 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1500 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 21.770(7) Å · b = 12.327(4) Å · c = 10.720(3) Å
Cell angles
β = 92.85(1) °
Ratio a:b:c
1 : 0.566 : 0.492
Unit cell volume
2873 ų
Z
4
Type-locality form

Aggregates of thin tabular crystals, flattened on (100) and elongated along [010], measuring up to 0.1 mm in length, 0.05 mm in width and 0.01 mm in thickness.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper1063.546635.460
41.44%
8OOxygenOxygen3415.999543.966
35.48%
33AsArsenicArsenic474.922299.688
19.54%
16SSulfurSulfur132.06032.060
2.09%
1HHydrogenHydrogen221.00822.176
1.45%
Total1533.350100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Si

Synonyms

  • IMA1998-032
  • Leogangiet

In other languages

German
IMA 1998-032 · Leogangit
Italian
Leogangite

Classification

Strunz
10th ed.

8.CC.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CCWith only medium-sized cations, RO4:H2O = 1:1.5Group
  • 8.CC.15LeogangiteSpecies

Literature, links & citation

Citations
  1. 1998Lengauer, C.L., Giester, G. and Kirchner, E. (1998) Cu10(AsO4)4(SO4)(OH)6.8H2O, ein neues Mineral aus Leogang, Österreich. Mitteilungen der Österreichischen Mineralogischen Gesellschaft: 143: 325-327. (in German)
  2. 2004Kirchner, E., Lengauer, C. L., Giester, G. (2004) Leogangite, Cu10(AsO4)4(SO4)(OH)6·8H2O, a new mineral from the Leogang mining district, Salzburg province, Austria. Mineralogy and Petrology, 81 (1) 187-201 doi:10.1007/s00710-004-0032-xDOI: 10.1007/s00710-004-0032-x
  3. 2005Putz, H., Lechner, A., Poeverlein, R. (2005) Leogangit von der Vogelhalt bei Leogang, Salzburg. Lapis: 30(10): 53-55; 90.
  4. 2008Schnorrer, G., Pfeiffer, F. (2008) Leogangit, Cu10[(OH)6|(AsO4)4|(SO4)]•8H2O, ein neues Mineral von der ehemaligen Grube Wildermann in Müsen im Siegerland. Der Aufschluss, 59 (6) 405-408
  5. 2011Frost, Ray L., Xi, Yunfei, Palmer, Sara J. (2011) The structure of the mineral leogangite Cu10(OH)6(SO4)(AsO4)4·8H2O—Implications for arsenic accumulation and removal. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 82 (1) 221-227 doi:10.1016/j.saa.2011.07.039DOI: 10.1016/j.saa.2011.07.039
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Leogangite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/leogangite-26518},
  note      = {Accessed 2026-05-11}
}