Libbyite

(NH4)2(Na2◻)[(UO2)2(SO4)3(H2O)]2 · 7H2O
IMA status
  • Approved
IMA symbol
Ly
Also known as
  • IMA2022-091
  • Libbyiet

Where it forms, where it's found

Geological setting

secondary assemblage

Type locality
Blue Lizard Mine
  1. Red Canyon Mining District
  2. San Juan County
  3. Utah
  4. USA

37.5572°, -110.2968°

1recorded occurrences
Source · OpenStreetMap

Radioactivity

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
light green
Streak
very pale green yellow
Tenacity
brittle
Cleavage
Very Good

excellent on (001)

Fracture
Sub-Conchoidal
Density
3.465 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.54 – 1.581
Surface relief
Moderate
Principal indices
nω 1.581 · nε 1.540
Pleochroism
Visible

The pleochroism is O yellow, E pale yellow; O > E.

UV response
strong green under 405 nm ultraviolet light.
Michel-Lévy diagramhighlighted lineδ = 0.0410
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]410 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation410 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
#167
Cell parameters
a = 10.704(1) Å · c = 31.824(2) Å
Z
4
Twinning

Merohedral twinning is likely because of the noncentrosymmetric space group, but was not observed.

Type-locality form

tightly intergrown aggregates of light green-yellow equant crystals

Crystal structure

Synonyms

  • IMA2022-091
  • Libbyiet

In other languages

German
IMA 2022-091 · Libbyit

Classification

Strunz
10th ed.

7.EC

  • 7SulfatesClass
  • 7.EUranyl sulfatesDivision
  • 7.ECWith medium-sized and large cationsGroup
  • 7.ECLibbyiteSpecies

Literature, links & citation

Citations
  1. 2022Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2022) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 70. European Journal of Mineralogy, 34 (6) 591-601 doi:10.5194/ejm-34-591-2022 DOI: 10.5194/ejm-34-591-2022
  2. 2023Kampf, Anthony R., Olds, Travis A., Plášil, Jakub, Nash, Barbara P., Marty, Joe (2023) Libbyite, (NH4)2(Na2□)[(UO2)2(SO4)3(H2O)]2⋅7H2O, a new mineral with uranyl–sulfate sheets from the Blue Lizard mine, San Juan County, Utah, USA. Mineralogical Magazine, 87 (5) 767-772 doi:10.1180/mgm.2023.26DOI: 10.1180/mgm.2023.26
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Libbyite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/libbyite-470492},
  note      = {Accessed 2026-05-11}
}