Liebauite

Ca3Cu5Si9O26
IMA status
  • Approved
IMA symbol
Lie
Discovered
1992
Also known as
  • IMA1990-040
  • Liebauiet

Where it forms, where it's found

Geological setting

argillaceous sedimentary xenoliths subjected to very high-grade thermal metamorphism.

Type locality
Nickenicher Weinberg
  1. Nickenich
  2. Pellenz
  3. Mayen-Koblenz
  4. Rhineland-Palatinate
  5. Germany

50.4050°, 7.3422°

2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105 – 6/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Greenish blue
Density
3.62 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 72° · 2V calc = 34°
Refractive index
1.722 – 1.734
Surface relief
High
Principal indices
nα 1.722 · nβ 1.723 · nγ 1.734
Pleochroism
Not Visible
Dispersion
r > v
Michel-Lévy diagramhighlighted lineδ = 0.0120
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]120 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation120 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 10.160(1) Å · b = 10.001(1) Å · c = 19.973(2) Å
Cell angles
β = 91.56(1) °
Ratio a:b:c
1 : 0.984 : 1.966
Z
4
Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2615.999415.974
37.59%
29CuCopperCopper563.546317.730
28.71%
14SiSiliconSilicon928.085252.765
22.84%
20CaCalciumCalcium340.078120.234
10.86%
Total1106.703100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1990-040
  • Liebauiet

In other languages

German
IMA 1990-040 · Liebauit
Italian
Liebauite

Classification

Strunz
10th ed.

9.DO.25

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DOInosilicates with 7-, 8-, 10-, 12- and 14-periodic chainsGroup
  • 9.DO.25LiebauiteSpecies
Dana
8th ed.

69.02.04.01

  • 69Inosilicates Chains with Side Branches or LoopsClass
  • 69.02Chains with Side Branches or Loops with P>2Type
  • 69.02.04— unnamed intermediate level —Group
  • 69.02.04.01LiebauiteSpecies

Literature, links & citation

Citations
  1. 1992Zöller, M.H., Tillmanns, E., Hentschel, G. (1992): Liebauite, Ca3Cu5Si9O26, a new silicate mineral with 14er single chain. Zeitschrift für Kristallographie, 200, 115-126.
  2. 1993Jambor, L., Burke, Ernst A. J., Grew, Edward S., Puziewicz, Jacek (1993) New Mineral Names. American Mineralogist, 78 (5-6) 672-678
  3. 1997Mandarino, Joseph A. (1997) New Minerals 1990-1994. The Mineralogical Record Inc., Tuscon, Arizona. 220pp.
  4. 2001(2001) Liebauite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Liebauite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/liebauite-2396},
  note      = {Accessed 2026-05-11}
}