Ludlockite

PbFe3+4As3+10O22
IMA status
  • Approved
IMA symbol
Ldl
Discovered
1970
Also known as
  • IMA1969-046
  • Ludlockiet
  • Ludlockite-(Pb)

Where it forms, where it's found

Type locality
Tsumeb Mine (Ongopolo Mine)
  1. Tsumeb
  2. Oshikoto Region
  3. Namibia

-19.2270°, 17.7276°

18recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789101.5 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Sub-Adamantine
Transparency
Translucent
Colour
Orange Red · orange brown
Streak
light brown
Tenacity
sectile
Cleavage
Perfect

(011), {0kl}

Fracture
None observed
Density
4.33 g/cm³

Optical

Optical type
Biaxial (+)
Refractive index
1.96 – 2.11
Surface relief
Very high
Principal indices
nα 1.96 · nβ 2.055 · nγ 2.11
Birefringence
0.15
Pleochroism
Visible

X yellow; Y deep yellow; Z orange yellow

Dispersion
strong
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.1500
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1500 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1500 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 10.41 Å · b = 11.95 Å · c = 9.86 Å
Cell angles
α = 113.9 ° · β = 99.7 ° · γ = 82.7 °
Ratio a:b:c
1 : 1.148 : 0.947
Z
9
Morphology

Hair-like crystals

Twinning

Lamellar twinning on (011), common.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic1074.922749.220
48.91%
8OOxygenOxygen2215.999351.978
22.98%
26FeIronIron455.845223.380
14.58%
82PbLeadLead1207.200207.200
13.53%
Total1531.778100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1969-046
  • Ludlockiet
  • Ludlockite-(Pb)

In other languages

French
Ludlockite
German
Ludlockit
Italian
Ludlockite · Ludlockite-(Pb)
Russian
Ludlockite

Classification

Strunz
10th ed.

4.JA.45

  • 4OxidesClass
  • 4.JArsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodatesDivision
  • 4.JAArsenites, antimonites, bismuthites; without additional anions, without H2OGroup
  • 4.JA.45LudlockiteSpecies
Dana
8th ed.

45.01.14.01

  • 45Acid and Normal Antimonites and ArsenitesClass
  • 45.01MiscellaneousType
  • 45.01.14— unnamed intermediate level —Group
  • 45.01.14.01LudlockiteSpecies
CIM

20.5.10

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.5Arsenates of Ti and PbGroup
  • 20.5.10LudlockiteSpecies

Literature, links & citation

Citations
  1. 1970Davis, R.J., Embrey, P.G., Hey, M.H. (1970) Ludlockite: A new arsenate mineral. Mineralogical Society of Japan Special Paper 1: 264-264.
  2. 1972Fleischer, Michael (1972) New mineral names. American Mineralogist, 57 (5-6). 1003-1006
  3. 1977Embrey, Peter G., Hey, Max H., Davis, Richard J. (1977) Ludlockite: a New Mineral from Tsumeb, in Tsumeb!. The Mineralogical Record, 8 (3) 91-94
  4. 1996Jambor, J.L., Kovalenker, V.A., Puziewics, J., Roberts, A.C. (1996) New mineral names. American Mineralogist: 81: 1282-1286.
  5. 1996Cooper, Mark A., Hawthorne, Frank C. (1996) The crystal structure of ludlockite, PbFe3+4As3+10O22, the mineral with pentameric arsenite groups and orange hair. The Canadian Mineralogist, 34 (1) 79-89
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ludlockite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ludlockite-2453},
  note      = {Accessed 2026-05-11}
}