Machatschkiite

Ca6(AsO4)(AsO3OH)3(PO4) · 15H2O
IMA status
  • Approved
IMA symbol
Mct
Discovered
1977
Also known as
  • IMA1976-010
  • Machatschkiiet
  • Unnamed (Ca Arsenate Sulphate)

Where it forms, where it's found

Type locality
Anton Mine
  1. Heubach Valley
  2. Wittichen
  3. Schenkenzell
  4. Rottweil
  5. Freiburg Region
  6. Baden-Württemberg
  7. Germany

48.3289°, 8.3233°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colorless
Cleavage
None Observed
Fracture
Conchoidal
Density
2.5 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.585 – 1.593
Surface relief
Moderate
Principal indices
nω 1.593 · nε 1.585
Michel-Lévy diagramhighlighted lineδ = 0.0080
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]80 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation80 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#85
Cell parameters
a = 15.127(2) Å · c = 22.471(3) Å
Z
6
Morphology

Pseudorhombohedral crystals, (1011) with minor (1012).

Type-locality form

crusts of subparallel pseudorhombohedral crystals,

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3515.999559.965
48.09%
33AsArsenicArsenic474.922299.688
25.74%
20CaCalciumCalcium640.078240.468
20.65%
1HHydrogenHydrogen331.00833.264
2.86%
15PPhosphorusPhosphorus130.97430.974
2.66%
Total1164.359100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1976-010
  • Machatschkiiet
  • Unnamed (Ca Arsenate Sulphate)

In other languages

German
IMA 1976-010 · Machatschkiit
Italian
Machatschkiite

Classification

Strunz
10th ed.

8.CJ.35

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CJWith only large cationsGroup
  • 8.CJ.35MachatschkiiteSpecies
Dana
8th ed.

39.03.08.01

  • 39Hydrated Acid Phosphates, Arsenates and VanadatesClass
  • 39.03MiscellaneousType
  • 39.03.08— unnamed intermediate level —Group
  • 39.03.08.01MachatschkiiteSpecies
CIM

22.3.3

  • 22Phosphates, Arsenates or Vanadates with other AnionsClass
  • 22.3Phosphates, arsenates or vanadates with sulphatesGroup
  • 22.3.3MachatschkiiteSpecies

Literature, links & citation

Citations
  1. 1977Fleischer, Michael, Cabri, Louis J., Pabst, and Adolf (1977) New mineral names. American Mineralogist, 62 (11-12) 1259-1262
  2. 1977Walenta, K. (1977) Machatschkiit, ein neues Arsenatmineral aus der Grube Anton im Heubachtal bei Schiltach (Schwarzwald, Bundesrepublik Deutschland). TMPM Tschermaks Mineralogische und Petrographische Mitteilungen, 24 (3). 125-132 doi:10.1007/bf01158190DOI: 10.1007/bf01158190
  3. 1982Effenberger, Herta, Mereiter, K., Pimminger, M., Zemann, J. (1982) Machatschkiite: Crystal structure and revision of the chemical formula. TMPM Tschermaks Mineralogische und Petrographische Mitteilungen, 30 (3). 145-155 doi:10.1007/bf01082326DOI: 10.1007/bf01082326
  4. 1982Fleischer, M., Burns, R.G., Cabri, L.J., Francis, C.A., Pabst, A. (1982) New mineral names. American Mineralogist, 67, 413-418.
  5. 1982Walenta, K., (1982) Zum Chemismus von Admontit und Machatschkiit. Schweizerische Mineralogische und Petrographische Mitteilungen: 62: 177-183.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Machatschkiite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/machatschkiite-2510},
  note      = {Accessed 2026-05-11}
}