Mahnertite

(Na,Ca,K)Cu3(AsO4)2Cl · 5H2O
IMA status
  • Approved
IMA symbol
Mah
Discovered
1994
IMA approved
1994
Also known as
  • IMA1994-035
  • Mahnertiet

Where it forms, where it's found

Geological setting

Oxidation product in a sedimentary-hosted copper deposit.

Type locality
Cap Garonne Mine
  1. Le Pradet
  2. Toulon
  3. Var
  4. Provence-Alpes-Côte d'Azur
  5. France

43.0814°, 6.0322°

9recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Translucent
Colour
Blue to emerald green.
Streak
Pale blue
Cleavage
Perfect

(001)

Fracture
Irregular/Uneven
Density
3.33 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.635 – 1.686
Surface relief
High
Principal indices
nω 1.686 · nε 1.635
Pleochroism
Strong
UV response
Not fluorescent
Notes

O = blue to intense green-blue, E = clear blue to clear green.

Michel-Lévy diagramhighlighted lineδ = 0.0510
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]510 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation510 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
#176
Cell parameters
a = 10.037 Å · c = 23.739 Å
Unit cell volume
2391.5 ų
Z
8
Morphology

Thin tetragonal plates. Tabular on (001), also showing (100).

Type-locality form

Blue to emerald green aggregates of thin (0.1 mm) square crystals, and as spherules to 0.2 mm in diameter.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1315.999207.987
29.88%
29CuCopperCopper363.546190.638
27.38%
33AsArsenicArsenic274.922149.844
21.52%
20CaCalciumCalcium140.07840.078
5.76%
19KPotassiumPotassium139.09839.098
5.62%
17ClChlorineChlorine135.45035.450
5.09%
11NaSodiumSodium122.99022.990
3.30%
1HHydrogenHydrogen101.00810.080
1.45%
Total696.165100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1994-035
  • Mahnertiet

In other languages

German
IMA 1994-035 · Mahnertit
Italian
Mahnertite

Classification

Strunz
10th ed.

8.DH.45

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
  • 8.DH.45MahnertiteSpecies

Literature, links & citation

Citations
  1. 1996Sarp, H. (1996) La mahnertite, (Na,Ca)Cu3(AsO4)2Cl·5H2O, un nouveau minéral de la mine de Cap Garonne, Var, France. Archives des Sciences, Genève, 49 (2) 119-124
  2. 1997Mandarino, Joseph A. (1997) Abstracts of New Mineral Descriptions. The Mineralogical Record, 28 (6) 483-486
  3. 1999Wendel, Wolfgang; Markl, Gregor (1999) Lavrion: Mineralogische Klassiker und Raritäten für Sammler [Lavrion: Mineralogical classics and rarities for collectors]. Lapis, 24 (7-8). 34-52; 90
  4. 2004Pushcharovsky, Dmitry . Y.u., Zubkova, Natalia V., Teat, Simon J., Maclean, Elizabeth, Sarp, Halil (2004) Crystal structure of mahnertite. European Journal of Mineralogy, 16 (4) 687-692 doi:10.1127/0935-1221/2004/0016-0687DOI: 10.1127/0935-1221/2004/0016-0687
  5. 2007Giester, Gerald; Kolitsch, Uwe; Leverett, Peter; Turner, Peter; Williams, Peter A. (2007) The crystal structures of lavendulan, sampleite, and a new polymorph of sampleite. European Journal of Mineralogy, 19 (1). 75-93 doi:10.1127/0935-1221/2007/0019-0075DOI: 10.1127/0935-1221/2007/0019-0075
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Mahnertite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/mahnertite-7165},
  note      = {Accessed 2026-05-11}
}