Makatite

Na2Si4O8(OH)2 · 4H2O
IMA status
  • Approved
IMA symbol
Mkt
IMA approved
1969
Also known as
  • IMA1969-003
  • Makatiet
  • Unnamed (MSH UK-66)

Where it forms, where it's found

Geological setting

Obtained from drill cores at depths of 8-30 meters. In cavities in coarsely crystalline trona, making up to 20% of the rock in places.

Type locality
Lake Magadi
  1. Kajiado County
  2. Kenya

-1.9091°, 36.2719°

9recorded occurrences
Source · OpenStreetMap

Physical

Colour
White
Streak
White
Cleavage
Perfect

Parallel to longitudinal axis

Density
1.97 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 70°
Refractive index
1.472 – 1.49
Surface relief
Low
Principal indices
nα 1.472 – 1.475 · nβ 1.48 · nγ 1.487 – 1.49
Dispersion
none
Michel-Lévy diagramhighlighted lineδ = 0.0150
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]150 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation150 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#14
Cell parameters
a = 7.388 Å · b = 18.094 Å · c = 9.523 Å
Cell angles
β = 90.64 °
Ratio a:b:c
1 : 2.449 : 1.289
Z
4
Morphology

Thin striated prisms. Typically as spherulites or fibrous radiating acicular aggregates.

Type-locality form

White spherulites or radiating acicular aggregates up to 3 mm in diameter. Individual crystals are 0.05-2.0 µm wide and 5-30 µm long. Commonly replacing trona.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1415.999223.986
57.08%
14SiSiliconSilicon428.085112.340
28.63%
11NaSodiumSodium222.99045.980
11.72%
1HHydrogenHydrogen101.00810.080
2.57%
Total392.386100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ti
  • Al
  • Fe
  • Mg
  • Ca
  • K

Synonyms

  • IMA1969-003
  • Makatiet
  • Unnamed (MSH UK-66)

In other languages

German
IMA 1969-003 · Makatit
Italian
Makatite

Classification

Strunz
10th ed.

9.EE.45

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.EESingle tetrahedral nets of 6-membered rings connected by octahedral nets or octahedral bandsGroup
  • 9.EE.45MakatiteSpecies
Dana
8th ed.

74.03.05.02

  • 74Phyllosilicates Modulated LayersClass
  • 74.03Modulated Layers with joined stripsType
  • 74.03.05Na phyllosilicatesGroup
  • 74.03.05.02MakatiteSpecies
CIM

14.1.4

  • 14Silicates not Containing AluminumClass
  • 14.1Silicates of the alkali metalsGroup
  • 14.1.4MakatiteSpecies

Literature, links & citation

Citations
  1. 1970Sheppard, Richard A., Gude, Arthur J. III, Hay, Richard L. (1970) Makatite, a new hydrous sodium silicate mineral from Lake Magadi, Kenya. American Mineralogist, 55 (3-4) 358-366
  2. 1980Khomyakov, A.P., Stepanov, V.I., Bykova, A.V., Naumova, I.S. (1980). Makatite (Na2Si4O9·5H2O) - the first discovery in the USSR. Doklady Academii Nauk SSSR, 255, 971-976. (in Russian)
  3. 1981Khomyakov, A.P., Stepanov, V.I., Bykova, Naumova, I.S. (1981). Makatite, Na2Si4O9•5H2O. Doklady Akademii Nauk SSSR, Earth Sciences Section, 255, 181-185.
  4. 1981Walenta, K., Zwiener, M., Telle, R. (1981) Seltene Mineralien aus dem Nephelinit-Steinbruch am Höwenegg im Hegau: Makatit und Paulingit. Der Aufschluss, 32 (4). 130-134
  5. 1982Annehed, H.; Fälth, L.; Lincoln, F. J. (1982) Crystal structure of synthetic makatite Na2Si4O8(OH)2 · 4H2O. Zeitschrift für Kristallographie, 159 (1-4). 203-210 doi:10.1524/zkri.1982.159.14.203DOI: 10.1524/zkri.1982.159.14.203
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Makatite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/makatite-2548},
  note      = {Accessed 2026-05-11}
}