Malladrite

Na2SiF6
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mld
Discovered
1926
Also known as
  • Malladriet

Where it forms, where it's found

Geological setting

Lava deposits on an active volcano.

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
5recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Pale rose · colorless · white
Cleavage
Perfect

(0001)

Density
2.714 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.309 – 1.313
Surface relief
Low
Principal indices
nω 1.313 · nε 1.309
Birefringence
weak
Michel-Lévy diagramhighlighted lineδ = 0.0040
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]40 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation40 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#90
Cell parameters
a = 8.86 Å · c = 5.04 Å
Morphology

Crystals prismatic [0001] with basal plane and pyramid. Tablets showing (0001), (1120), and (1010) (Serafimova et al. 1996)

Comment

synthetic

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
9FFluorineFluorine618.998113.988
60.62%
11NaSodiumSodium222.99045.980
24.45%
14SiSiliconSilicon128.08528.085
14.93%
Total188.053100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Malladriet

In other languages

German
Malladrit
Italian
Malladrite
Russian
малладрит

Classification

Strunz
10th ed.

3.CH.05

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.CHSilicofluoridesGroup
  • 3.CH.05MalladriteSpecies
Dana
8th ed.

11.05.02.01

  • 11Halide ComplexesClass
  • 11.05AmBX6Type
  • 11.05.02Malladrite GroupGroup
  • 11.05.02.01MalladriteSpecies
CIM

8.12.3

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.12— unnamed intermediate level —Group
  • 8.12.3MalladriteSpecies

Literature, links & citation

Citations
  1. 1872Stolba (1872) Zeitschrift für anorganische und allgemeine Chemie, Hamburg, Leipzig: 11: 199.
  2. 1880Bertrand (1880) Bulletin de la Société française de Minéralogie: 3: 57.
  3. 1922Raiteri (1922) Reale accademia nazionale dei Lincei, Rendus, Rome: 31: 115.
  4. 1926Zambonini, F., Carobbi, G. (1926) Sulla presenza del fluosilicato sodico e di quello di potassio tra i prodotti dell'attuale attivita del Vesuvio. Rendiconti, Reale Accademia dei Lincei: 4: 171-175.
  5. 1927Foshag, W.F. (1927) New Mineral Names. American Mineralogist, 12 (10). 379-380
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Malladrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/malladrite-2554},
  note      = {Accessed 2026-05-11}
}