Mapimite

Zn2Fe3+3(AsO4)3(OH)4 · 10H2O
IMA status
  • Approved
IMA symbol
Mpm
Discovered
1978
IMA approved
1978
Also known as
  • IMA1978-070
  • Mapimiet

Where it forms, where it's found

Type locality
Ojuela Mine
  1. Mapimí
  2. Mapimí Municipality
  3. Durango
  4. Mexico

25.7936°, -103.7911°

2recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Blue · blue-green · green

variable due to trichroism

Cleavage
Distinct/Good

(001) and (010).

Density
2.95 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 50° · 2V calc = 48°
Refractive index
1.672 – 1.712
Surface relief
High
Principal indices
nα 1.672 · nβ 1.678 · nγ 1.712
Pleochroism
Strong

X = pale yellow; Y = greenish yellow; Z = deep Prussian blue

Dispersion
r > v strong
Extinction
Y = b, Z ∧ a = 13°.
Michel-Lévy diagramhighlighted lineδ = 0.0400
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]400 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation400 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
Cm
Cell parameters
a = 11.415(5) Å · b = 11.259(5) Å · c = 8.661(3) Å
Cell angles
β = 107.74(4) °
Ratio a:b:c
1 : 0.986 : 0.759
Z
2
Twinning

Polysynthetic on (001) with [104] pseudoaxis.

Type-locality form

rectangular tabular crystals

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2615.999415.974
43.19%
33AsArsenicArsenic374.922224.766
23.33%
26FeIronIron355.845167.535
17.39%
30ZnZincZinc265.380130.760
13.58%
1HHydrogenHydrogen241.00824.192
2.51%
Total963.227100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1978-070
  • Mapimiet

In other languages

German
IMA 1978-070 · Mapimit
Italian
Mapimite

Classification

Strunz
10th ed.

8.DC.55

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DCWith only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1Group
  • 8.DC.55MapimiteSpecies
Dana
8th ed.

42.08.07.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.08(AB)5(XO4)3Zq·xH2OType
  • 42.08.07— unnamed intermediate level —Group
  • 42.08.07.01MapimiteSpecies
CIM

20.9.15

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.9Arsenates of FeGroup
  • 20.9.15MapimiteSpecies

Literature, links & citation

Citations
  1. 1981Cesbron, Fabien, Romero S., Miguel, Williams, Sydney A. (1981) La mapimite et l'ojuélaïte, deux nouveaux arséniates hydratés de zinc et de fer de la mine Ojuela, Mapimi, Mexique. Bulletin de Minéralogie, 104 (4) 582-586 doi:10.3406/bulmi.1981.7510 DOI: 10.3406/bulmi.1981.7510
  2. 1981Ginderow, D., Cesbron, F. (1981) Structure de la mapimite, Zn2Fe3(AsO4)3(OH)4·10H2O. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 37 (5) 1040-1043 doi:10.1107/s0567740881005025DOI: 10.1107/s0567740881005025
  3. 1982Fleischer, M., Cabri, L.J., Chao, G.Y., Mandarino, J.A., Pabst, A. (1982) New mineral names. American Mineralogist: 67: 621-624.
  4. 2005(2005) Mapimite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Mapimite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/mapimite-2570},
  note      = {Accessed 2026-05-11}
}