Martinite

(Na,◻,Ca)12Ca4(Si,S,B)14B2O38(OH,Cl)2F2 · 4H2O
IMA status
  • Approved
IMA symbol
Mrt
IMA approved
2001
Also known as
  • IMA2001-059
  • Martiniet
  • Unnamed (MSH UK-92)

Where it forms, where it's found

Geological setting

Formed through the interaction of highly fractionated, hyperagpaitic fluids with sodalite syenite xenoliths.

Type locality
Poudrette quarry (De-Mix quarry
  1. Demix quarry
  2. Uni-Mix quarry
  3. Carrière Mont Saint-Hilaire
  4. MSH)
  5. Mont Saint-Hilaire
  6. La Vallée-du-Richelieu RCM
  7. Montérégie
  8. Québec
  9. Canada

45.5628°, -73.1417°

2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless · mauve · purple
Streak
White
Tenacity
brittle
Cleavage
Perfect

On (001).

Inelastic

Fracture
Irregular/Uneven
Density
2.51 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 38° · 2V calc = 35°
Refractive index
1.529 – 1.551
Surface relief
Moderate
Principal indices
nα 1.529 · nβ 1.549 · nγ 1.551
Pleochroism
Non-pleochroic
Dispersion
None observed.
Extinction
X ≈ c.
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0220
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]220 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation220 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
P-1
Cell parameters
a = 9.5437 Å · b = 9.5349 Å · c = 14.0268 Å
Cell angles
α = 108.943 ° · β = 74.154 ° · γ = 119.780 °
Ratio a:b:c
1 : 0.999 : 1.470
Unit cell volume
1038.1 ų
Z
2
Morphology

Triangular to roughly hexagonal plates dominated by (001).

Type-locality form

Single crystals and as rosettes of triangular to roughly hexagonal plates varying from 50 µm to a maximum of about 1 mm across. Individual crystals are typically <10 µm in thickness.

Crystal structure

Synonyms

  • IMA2001-059
  • Martiniet
  • Unnamed (MSH UK-92)

In other languages

German
IMA 2001-059 · Martinit
Spanish
Martinita
Italian
Martinite

Classification

Strunz
10th ed.

9.EE.80

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.EESingle tetrahedral nets of 6-membered rings connected by octahedral nets or octahedral bandsGroup
  • 9.EE.80MartiniteSpecies

Group, growth & confusion

In the same group
1 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1996Grew, Edward S.; Anovitz, Lawrence M. - Eds. (1996) Boron - Mineralogy, Petrology and Geochemistry. Reviews in Mineralogy Vol. 33. Mineralogical Society of America p.862
  2. 2007McDonald, Andrew M., Chao, George Y. (2007) Martinite, a new hydrated sodium calcium fluorborosilicate species from Mont Saint-Hilaire, Quebec: description, structure determination and genetic implications. The Canadian Mineralogist, 45 (5) 1281-1292 doi:10.2113/gscanmin.45.5.1281 DOI: 10.2113/gscanmin.45.5.1281
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Martinite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/martinite-26345},
  note      = {Accessed 2026-05-11}
}