Masaitisite

KCu5O2(SeO3)2Cl3
IMA status
  • Approved
IMA symbol
Msts
IMA approved
2023
Also known as
  • Masaitisiet

Where it forms, where it's found

Geological setting

high-temperature sublimes of the active fumarole Yadovitaya at the Second scoria cone of the Northern Breakthrough of the Great Tolbachik Fissure Eruption, Tolbachik volcano, Kamchatka, Russia.

Type locality
Yadovitaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.8333°, 160.3333°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Transparent
Colour
bright yellowish-green
Tenacity
brittle
Cleavage
None Observed
Density
4.01 g/cm³

Optical

Optical colour
gray
Anisotropism
from brownish-gray to dark brownish-gray.
Bireflectance
weak
Internal reflections
weak light green
Tropism
Anisotropic
Reflectance R%
(8.1,10.9) 470, (9.8,11.3) 546, (9.2,10.4) 589, (7.9,9.8) 650
Reflected-light panel
8.8 %anisotropic · dual curve
Specimen sRGB 112, 80, 37
White reference100 % reflector under same lamp
R₁ R₂
Mode
Bireflectance
weak
Anisotropism
from brownish-gray to dark brownish-gray.
Reflected colour
gray
Internal reflections
weak light green

Crystallography

Crystal system
Orthorhombic
Space group
Pnma
Cell parameters
a = 18.154(5) Å · b = 6.451(2) Å · c = 10.567(3) Å
Ratio a:b:c
1 : 0.355 : 0.582
Z
4
Type-locality form

occurs as prismatic, tabular or lamellar crystals up to 30μm long, up to 20μm wide, and up to 5μm thick. The crystals are combined in aggregates up to 0.2mm overgrowing euchlorine crusts.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper563.546317.730
42.41%
34SeSeleniumSelenium278.971157.942
21.08%
8OOxygenOxygen815.999127.992
17.09%
17ClChlorineChlorine335.450106.350
14.20%
19KPotassiumPotassium139.09839.098
5.22%
Total749.112100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From Mindat formula

Synonyms

  • Masaitisiet

In other languages

German
IMA 2023-021 · Masaitisit

Classification

Strunz
10th ed.

4.JG

  • 4OxidesClass
  • 4.JArsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodatesDivision
  • 4.JGSelenites with additional anions, without H2OGroup
  • 4.JGMasaitisiteSpecies

Literature, links & citation

Citations
  1. 2023Bosi, Ferdinando; Hatert, Frédéric; Pasero, Marco; Mills, Stuart J. (2023) Newsletter 74. Mineralogical Magazine, 87 (5). 783-787 doi:10.1180/mgm.2023.54DOI: 10.1180/mgm.2023.54
  2. 2025Pekov, I. V; Murashko, M. N; Agakhanov, A. A; Vigasina, M. F; Britvin, S. N; Turchkova, A. G (2025) Masaitisite, KCu 5 O 2 (Se 4+ O 3 ) 2 Cl 3 , a New Mineral from Fumarole Exhalations of the Tolbachik Volcano, Kamchatka, Russia. Zapiski of the Russian Mineralogical Society, CLIV (6). 27-39
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Masaitisite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/masaitisite-470831},
  note      = {Accessed 2026-05-11}
}