Masuyite

Pb(UO2)3O3(OH)2 · 3H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Msy
Discovered
1947
Also known as
  • Masuyiet

Where it forms, where it's found

Type locality
Shinkolobwe Mine
  1. Shinkolobwe
  2. Kambove Territory
  3. Haut-Katanga
  4. DR Congo

-11.0486°, 26.5508°

26recorded occurrences
Source · OpenStreetMap

Radioactivity

Physical

Transparency
Transparent
Colour
Red-orange · orange · brownish orange.
Cleavage
Perfect

(001), perfect; (010), good.

Density
5.08 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 40 – 50° · 2V calc = 44°
Refractive index
1.785 – 1.917
Surface relief
Very high
Principal indices
nα 1.785 · nβ 1.895 – 1.906 · nγ 1.915 – 1.917
Pleochroism
Weak

X = pale yellow; Y = Z = deep golden yellow

Dispersion
extreme
Michel-Lévy diagramhighlighted lineδ = 0.1310
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1310 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1310 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 13.98(10) Å · b = 12.17(27) Å · c = 14.56(36) Å
Ratio a:b:c
1 : 0.871 : 1.041
Z
2
Twinning

Very common on (110) or (130) as twin and composition planes, contact and repeated, individuals with parallel to (001).

Type-locality form

Small (0.1 mm), pseudo-hexagonal, orange-red scales.

Comment

Space Group: P cna, probable, pseudocell.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
92UUraniumUranium3238.029714.087
61.91%
8OOxygenOxygen1415.999223.986
19.42%
82PbLeadLead1207.200207.200
17.97%
1HHydrogenHydrogen81.0088.064
0.70%
Total1153.337100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Masuyiet

In other languages

German
Masuyit
Spanish
Masuyita
Italian
Masuyite
Arabic
ماسوييت

Classification

Strunz
10th ed.

4.GB.35

  • 4OxidesClass
  • 4.GUranyl HydroxidesDivision
  • 4.GBWith additional cations (K, Ca, Ba, Pb, etc.); with mainly UO2(O,OH)5 pentagonal polyhedraGroup
  • 4.GB.35MasuyiteSpecies
Dana
8th ed.

05.02.02.01

  • 05Oxides Containing Uranium or ThoriumClass
  • 05.02AXO3·xH2OType
  • 05.02.02— unnamed intermediate level —Group
  • 05.02.02.01MasuyiteSpecies
CIM

7.16.27

  • 7Oxides and HydroxidesClass
  • 7.16Oxides of UGroup
  • 7.16.27MasuyiteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. www.mindat.org (n.d.) https://www.mindat.org/mesg-7-446504.html
  2. 1947Vaes, J.F. (1947) Six nouveaux minéraux d'urane provenant de Shinkolobwe (Katanga). Annales de la Société Géologique Belge: 70: B212-B229.
  3. 1948Fleischer, M. (1948) New mineral names. American Mineralogist, 33 (5-6). 384-386
  4. 1996Deliens, M., Piret, P. (1996) Les masuyites de Shinkolobwe constituent un groupe formé par deux variétés distinctes par leur composition chimique et leurs propriétés radiocristallographiques. Bulletin de l'Institut Royal des Sciences Naturelles de Belgique: 66: 187-192. (in French)
  5. 1999Burns, P. C., Hanchar, J. M. (1999) The structure of masuyite, Pb[(UO2)3O3(OH)2](H2O)3, and its relationship to protasite. The Canadian Mineralogist, 37 (6) 1483-1491
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Masuyite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/masuyite-2589},
  note      = {Accessed 2026-05-11}
}