Matteuccite

NaH(SO4) · H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mtt
Also known as
  • Matteucciet

Where it forms, where it's found

Geological setting

stalactites formed in a volcanic crater

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
1recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Translucent
Colour
colorless
Density
2.118 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 86° · 2V calc = 76°
Refractive index
1.43 – 1.48
Surface relief
Low
Principal indices
nα 1.43 · nβ 1.46 · nγ 1.48
Dispersion
none
Michel-Lévy diagramhighlighted lineδ = 0.0500
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]500 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation500 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 8.213 Å · b = 7.812 Å · c = 7.805 Å
Cell angles
β = 120.04 °
Ratio a:b:c
1 : 0.951 : 0.950
Z
4
Type-locality form

massive component of fumarolic stalactites

Comment

Space Group: Aa (synthetic).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen515.99979.995
57.94%
16SSulfurSulfur132.06032.060
23.22%
11NaSodiumSodium122.99022.990
16.65%
1HHydrogenHydrogen31.0083.024
2.19%
Total138.069100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Matteucciet

In other languages

German
Matteuccit
Italian
Matteuccite

Classification

Strunz
10th ed.

7.CD.05

  • 7SulfatesClass
  • 7.CSulfates (selenates, etc.) without additional anions, with H2ODivision
  • 7.CDWith only large cationsGroup
  • 7.CD.05MatteucciteSpecies
Dana
8th ed.

29.01.02.01

  • 29Hydrated Acid and Normal SulfatesClass
  • 29.01Hydrated Acid SulfatesType
  • 29.01.02— unnamed intermediate level —Group
  • 29.01.02.01MatteucciteSpecies
CIM

25.1.2

  • 25SulphatesClass
  • 25.1Sulphates of the alkali metals and ammoniumGroup
  • 25.1.2MatteucciteSpecies

Literature, links & citation

Citations
  1. 1952Carobbi, G., Cipriani, C. (1952) Matteuccite: nuovo minerale vesuviano. Rendiconti della Società Mineralogica Italiana: 8: 54. (in Italian)
  2. 1952Carobbi, G., Cipriani, C. (1952) Ralstonite e bisolfato sodico (matteuccite) fra i prodotti delle fumarole vesuviane. Rendiconti dell’Accademia Nazionale dei Lincei, Serie VIII: 12: 23-29. (in Italian)
  3. 1952Carobbi, G., Cipriani, C. (1952) Matteuccite: nuovo minerale vesuviano. Rendiconti della Società Mineralogica Italiana: 8: 54
  4. 1954Fleischer, M. (1954) New mineral names. American Mineralogist, 39 (9-10). 848-852
  5. 1965Pringle, G.E., Broadbent, T.A. (1965) X-ray structure analysis of sodium hydrogen sulphate monohydrate. Acta Crystallographica: 19: 426-432.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Matteuccite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/matteuccite-2596},
  note      = {Accessed 2026-05-11}
}