Medaite

Mn2+6V5+Si5O18(OH)
IMA status
  • Approved
IMA symbol
Med
Discovered
1982
Also known as
  • IMA1979-062
  • Medaiet

Where it forms, where it's found

Geological setting

Manganese mine.

Type locality
Molinello Mine
  1. Ne
  2. Genoa
  3. Liguria
  4. Italy

44.3453°, 9.4589°

8recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Translucent
Colour
Brownish-red
Tenacity
brittle
Cleavage
Distinct/Good

(100) good

Density
3.65 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 71° · 2V calc = 72°
Refractive index
1.77 – 1.8
Surface relief
High
Principal indices
nα 1.77 · nβ 1.78 · nγ 1.80
Pleochroism
Weak

Dark to lighter orange

Dispersion
r > v distinct
Notes

X = a; Y = b; Z = c; X Λ ⊥ to cleavage = 3°.

Michel-Lévy diagramhighlighted lineδ = 0.0300
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]300 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation300 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 6.712(1) Å · b = 28.948(8) Å · c = 7.578(2) Å
Cell angles
β = 95.4(2) °
Ratio a:b:c
1 : 4.313 : 1.129
Z
4
Twinning

Microscopic symmetrical twinning. The twin plane is coincident with (100).

Parting
Distinct normal to elongation
Type-locality form

Small brown grains embedded in brownish veinlets, a few millimeters thick, cutting a black Mn ore made up mainly of quartz and braunite. The grains reach 1.5 mm but are usually smaller. They are usually embedded in quartz.

Comment

Space Group: P21/n:

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese654.938329.628
39.91%
8OOxygenOxygen1915.999303.981
36.80%
14SiSiliconSilicon528.085140.425
17.00%
23VVanadiumVanadium150.94250.942
6.17%
1HHydrogenHydrogen11.0081.008
0.12%
Total825.984100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • H2O

Synonyms

  • IMA1979-062
  • Medaiet

In other languages

German
IMA 1979-062 · Medait
Italian
Medaite
Portuguese
IMA1979-062

Classification

Strunz
10th ed.

9.BJ.30

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BJSorosilicates with Si3O10, Si4O11, etc. anions; cations in octahedral [6] and greater coordinationGroup
  • 9.BJ.30MedaiteSpecies
Dana
8th ed.

57.04.01.01

  • 57Sorosilicates Si3o10 Groups and Larger Noncyclic GroupsClass
  • 57.04Insular Si3O10 and Larger Noncyclic Groups with groups with 6 or more tetrahedraType
  • 57.04.01— unnamed intermediate level —Group
  • 57.04.01.01MedaiteSpecies
CIM

17.7.5

  • 17Silicates Containing other AnionsClass
  • 17.7Silicates with vanadate, arsenate or antimonateGroup
  • 17.7.5MedaiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1981Gramaccioli, C. M.; Liborio, G.; Pilati, T. (1981) Structure of medaite, Mn6[VSi5O18(OH)]: the presence of a new kind of heteropolysilicate anion. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 37 (11). 1972-1978 doi:10.1107/s0567740881007796DOI: 10.1107/s0567740881007796
  2. 1982Gramaccioli, C.M., Griffin, W.L., Mottana, A. (1982) Medaite, Mn6[VSi5O18(OH)], a new mineral and the first example of vanadatopentasilicate ion. American Mineralogist: 67: 85-89.
  3. 2001(2001) Medaite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2010Nagashima, M., Armbruster, T. (2010) Ardennite, tiragalloite and medaite: structural control of (As5+,V5+,Si4+)O4 tetrahedra in silicates. Mineralogical Magazine, 74 (1) 55-71 doi:10.1180/minmag.2010.074.1.55DOI: 10.1180/minmag.2010.074.1.55
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Medaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/medaite-2624},
  note      = {Accessed 2026-05-11}
}