Medenbachite

Bi2Fe3+Cu2+(AsO4)2O(OH)3
IMA status
  • Approved
IMA symbol
Mdb
Discovered
1984
IMA approved
1993
Also known as
  • IMA1993-048
  • Medenbachiet

Where it forms, where it's found

Geological setting

Weathering of small ore impregnations in a silicified barite vein.

Type locality
Point 8.0
  1. Borstein
  2. Reichenbach
  3. Lautertal (Odenwald)
  4. Bergstraße
  5. Darmstadt
  6. Hesse
  7. Germany

49.7127°, 8.6837°

5recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous to Adamantine
Transparency
Transparent · Translucent
Colour
Yellow to brown-yellow
Cleavage
None Observed
Fracture
Conchoidal
Density
5.90 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 43° · 2V calc = 42°
Refractive index
2.03 – 2.1
Surface relief
Very high
Principal indices
nα 2.03 · nβ 2.09 · nγ 2.1
Dispersion
r > v
UV response
None
Michel-Lévy diagramhighlighted lineδ = 0.0700
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]700 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation700 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 4.57 Å · b = 6.162 Å · c = 8.993 Å
Cell angles
α = 94.56 ° · β = 99.69 ° · γ = 94.28 °
Ratio a:b:c
1 : 1.348 : 1.968
Unit cell volume
247.84 ų
Z
1
Morphology

The crystals are tabular on {-101} and slightly elongated parallel to [111]. They exhibit two main zones: One is parallel to [111] and includes {-101}, {-110}, {0-11}, and the other is parallel to [010] and includes {-101}, (101), and (001).

Type-locality form

Very small, intergrown, tabular crystals up to 0.2 mm in length, often forming aggregates of parallel intergrowths, which crystallize within cavernous quartz.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
83BiBismuthBismuth2208.980417.960
47.38%
8OOxygenOxygen1215.999191.988
21.76%
33AsArsenicArsenic274.922149.844
16.99%
29CuCopperCopper163.54663.546
7.20%
26FeIronIron155.84555.845
6.33%
1HHydrogenHydrogen31.0083.024
0.34%
Total882.207100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1993-048
  • Medenbachiet

In other languages

German
IMA 1993-048 · Medenbachit
Italian
Medenbachite

Classification

Strunz
10th ed.

8.BK.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BKWith medium-sized and large cations, (OH, etc.):RO4 = 2:1, 2.5:1Group
  • 8.BK.10MedenbachiteSpecies

Literature, links & citation

Citations
  1. 1996Mandarino, Joseph A. (1996) Abstracts of New Mineral Descriptions. The Mineralogical Record, 27 (6) 463-466
  2. 1996Krause, Werner, Bernhardt, Heinz-Juergen, Gebert, Walter, Graetsch, Heribert, Belendorff, Klaus, Petitjean, Klaus (1996) Medenbachite, Bi2Fe(Cu,Fe)(O,OH)2(OH)2(AsO4)2, a new mineral species; its description and crystal structure. American Mineralogist, 81 (3) 505-512 doi:10.2138/am-1996-3-424 DOI: 10.2138/am-1996-3-424
  3. 2002Krause, Werner, Bernhardt, Heinz-Jürgen, McCammon, Catherine, Effenberger, Herta (2002) Neustädtelite and cobaltneustädtelite, the Fe3+- and Co2+-analogues of medenbachite. American Mineralogist, 87 (5) 726-738 doi:10.2138/am-2002-5-616 DOI: 10.2138/am-2002-5-616
  4. 2005(2005) Medenbachite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Medenbachite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/medenbachite-2625},
  note      = {Accessed 2026-05-11}
}