Melanarsite

K3Cu7Fe3+O4(AsO4)4
IMA status
  • Approved
IMA symbol
Mea
IMA approved
2014
Also known as
  • IMA2014-048
  • Melanarsiet

Where it forms, where it's found

Geological setting

Fumaroles

Type locality
Arsenatnaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.6833°, 160.2333°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Black
Streak
Dark green with an olive hue
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
4.39 g/cm³

Optical

Optical type
Biaxial
Refractive index
1.8 – 1.91
Surface relief
Very high
Principal indices
nα 1.80 · nγ 1.91
Pleochroism
Weak

Observed in the thinnest particles, is strong with Z (very dark greyish-green) > X (green to pale green).

Optical colour
Dark grey
Anisotropism
Very weak
Bireflectance
Weak
Tropism
Anisotropic
Reflectance R%
(11.4,10.2) 400, (11.1,9.9) 420, (10.9,9.7) 440, (10.6,9.4) 460, (10.5,9.4) 470, (10.4,9.3) 480, (10.2,9.1) 500, (10.1,9.0) 520, (10.0,8.9) 540, (10.0,8.9) 546, (9.9,8.8) 560, (9.8,8.7) 580, (9.7,8.7) 589, (9.7,8.7) 600, (9.6,8.6) 620, (9.5,8.6) 640, (9.5,8.6) 650, (9.4,8.5) 660, (9.4,8.4) 680, (9.3,8.4) 700
Notes

Optical sign, β, and 2V not determined.

Reflected-light panel
10.1 %anisotropic · dual curve
Specimen sRGB 118, 82, 45
White reference100 % reflector under same lamp
R₁ R₂
Mode
Bireflectance
Weak
Anisotropism
Very weak
Reflected colour
Dark grey

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 11.4763(9) Å · b = 16.620(2) Å · c = 10.1322(8) Å
Cell angles
β = 105.078(9) °
Ratio a:b:c
1 : 1.448 : 0.883
Z
4
Morphology

Tabular to prismatic crystals up to 0.4 mm; clusters; forming crust

Type-locality form

Tabular to prismatic crystals up to 0.4 mm, separate or combined in clusters up to 1 mm across or in interrupted crusts up to 0.02 x 1 x 1 cm covering basalt scoria.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper763.546444.822
35.94%
8OOxygenOxygen2015.999319.980
25.85%
33AsArsenicArsenic474.922299.688
24.22%
19KPotassiumPotassium339.098117.294
9.48%
26FeIronIron155.84555.845
4.51%
Total1237.629100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Zn

Synonyms

  • IMA2014-048
  • Melanarsiet

In other languages

German
IMA 2014-048 · Melanarsit
Italian
melanarsite

Classification

Strunz
10th ed.

8.BH.75

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BHWith medium-sized and large cations, (OH,etc.):RO4 = 1:1Group
  • 8.BH.75MelanarsiteSpecies

Literature, links & citation

Citations
  1. 2014Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2014) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC), CNMNC Newsletter No. 22. Mineralogical Magazine, 78 (5) 1241-1248 doi:10.1180/minmag.2014.078.5.10DOI: 10.1180/minmag.2014.078.5.10
  2. 2016Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Polekhovsky, Yury S., Vigasina, Marina F., Belakovskiy, Dmitry I., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Y. (2016) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. VI. Melanarsite, K3Cu7Fe3+O4(AsO4)4. Mineralogical Magazine, 80 (5) 855-867 doi:10.1180/minmag.2016.080.027 DOI: 10.1180/minmag.2016.080.027
  3. 2017(2017) Melanarsite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Melanarsite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/melanarsite-46427},
  note      = {Accessed 2026-05-11}
}