Melanothallite

Cu2OCl2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mlth
Discovered
1870
Also known as
  • Melanotallo
  • Melanothalliet
  • Melanothallite (of Scacchi)

Where it forms, where it's found

Geological setting

Fumaroles.

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
5recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Opaque
Colour
Black · bluish black

Changes to green colours upon exposure.

Tenacity
brittle
Cleavage
Perfect

One direction, perfect, probably prismatic

Density
4.08 g/cm³

Optical

Optical type
Biaxial
Notes

Deep brown in transmitted light.

Crystallography

Crystal system
Orthorhombic
Space group
Fddd
Cell parameters
a = 9.595(3) Å · b = 9.693(3) Å · c = 7.461(3) Å
Ratio a:b:c
1 : 1.010 : 0.778
Z
8
Type-locality form

Platy or scaly, to 1 cm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper263.546127.092
59.39%
17ClChlorineChlorine235.45070.900
33.13%
8OOxygenOxygen115.99915.999
7.48%
Total213.991100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Melanotallo
  • Melanothalliet
  • Melanothallite (of Scacchi)

In other languages

German
Melanothallit
Italian
Melanotallite · Melanothallite

Classification

Strunz
10th ed.

3.DA.05

  • 3HalidesClass
  • 3.DOxyhalides, hydroxyhalides and related double halidesDivision
  • 3.DAWith Cu, etc., without PbGroup
  • 3.DA.05MelanothalliteSpecies
Dana
8th ed.

10.04.04.01

  • 10Oxyhalides and HydroxyhalidesClass
  • 10.04A2(O,OH)XqType
  • 10.04.04— unnamed intermediate level —Group
  • 10.04.04.01MelanothalliteSpecies
CIM

8.2.7

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.2Halides of CuGroup
  • 8.2.7MelanothalliteSpecies

Literature, links & citation

Citations
  1. 1870Scacchi, A. (1870) Dell'eriocalco e del melanotallo, nuove specie di minerali. Rendiconto dell'Accademia delle Scienze Fisiche e Matematiche (sezione della Societa reale di Napoli): 9: 86-89.
  2. 1884Scacchi, A. (1884) Reale Accademia delle Scienze Fisiche e Matematiche, Naples, Rend.: 10: 158.
  3. 1935Zambonini, Ferruccio (1935) Mineralogia Vesuviana. second edition with Quercigh, 463 pp., Naples: 111-112.
  4. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  5. 1982Bergasova, L.P., Filatov, S.K. (1982) The chemical formula and crystallochemical characteristics of melanothallite, Cu2OCl2. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva, 111(5), 562-565.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Melanothallite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/melanothallite-2623},
  note      = {Accessed 2026-05-11}
}