Mercallite

KH(SO4)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mec
Discovered
1935
Also known as
  • Mercalliet

Where it forms, where it's found

Geological setting

Active volcanic fumaroles.

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
5recorded occurrences
Source · OpenStreetMap

Physical

Lustre
Vitreous
Transparency
Transparent
Colour
Colourless · sky-blue · colourless in transmitted light
Cleavage
None Observed
Density
2.31 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 56° · 2V calc = 72°
Refractive index
1.445 – 1.491
Surface relief
Low
Principal indices
nα 1.445 · nβ 1.460 · nγ 1.491
Dispersion
relatively strong
Michel-Lévy diagramhighlighted lineδ = 0.0460
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]460 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation460 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Pbca
Cell parameters
a = 8.429(3) Å · b = 18.976(3) Å · c = 9.807(3) Å
Ratio a:b:c
1 : 2.251 : 1.163
Z
16
Morphology

Stalactites composed of minute tabular crystals. Crystals tabular (001) and elongated [100] at times (artificial).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
47.00%
19KPotassiumPotassium139.09839.098
28.71%
16SSulfurSulfur132.06032.060
23.55%
1HHydrogenHydrogen11.0081.008
0.74%
Total136.162100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Mercalliet

In other languages

German
Mercallit
Italian
Mercallite

Classification

Strunz
10th ed.

7.AD.10

  • 7SulfatesClass
  • 7.ASulfates (selenates, etc.) without additional anions, without H2ODivision
  • 7.ADWith only large cationsGroup
  • 7.AD.10MercalliteSpecies
Dana
8th ed.

28.01.01.01

  • 28Anhydrous Acid and Normal SulfatesClass
  • 28.01Anhydrous Acid SulfatesType
  • 28.01.01— unnamed intermediate level —Group
  • 28.01.01.01MercalliteSpecies
CIM

25.1.5

  • 25SulphatesClass
  • 25.1Sulphates of the alkali metals and ammoniumGroup
  • 25.1.5MercalliteSpecies

Literature, links & citation

Citations
  1. 1856Marignac, J.C. (1856) Annales des mines [5]: 9: 6. (artificial)
  2. 1856Marignac, J.C. (1856) Oeuvres: 1: 436. (artificial)
  3. 1858Lang (1858) Konigliche Akademie der Wissenschaften, Vienna, Sitzber.: 51: 95.
  4. 1904Gossner, B. (1904) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 39: 381.
  5. 1908Groth, P. (1908) Chemische Krystallographie Vol. 2. Wilhem Engelmann.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Mercallite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/mercallite-2646},
  note      = {Accessed 2026-05-11}
}