Where it forms, where it's found
- Geological setting
Active volcanic fumaroles.
- Type locality
- Mount Vesuvius
- Metropolitan City of Naples
- Campania
- Italy
5recorded occurrences
Physical
- Lustre
- Vitreous
- Transparency
- Transparent
- Colour
- Colourless · sky-blue · colourless in transmitted light
- Cleavage
- None Observed
- Density
- 2.31 g/cm³
Optical
- Optical type
- Biaxial (+) · 2V measured = 56° · 2V calc = 72°
- Refractive index
- 1.445 – 1.491
- Principal indices
- nα 1.445 · nβ 1.460 · nγ 1.491
- Dispersion
- relatively strong
Δ = 0Δmax
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation460 nm
Order1st order
XPL colour
Crystallography
- Space group
- Pbca
- Cell parameters
- a = 8.429(3) Å · b = 18.976(3) Å · c = 9.807(3) Å
- Ratio a:b:c
- 1 : 2.251 : 1.163
- Z
- 16
- Morphology
Stalactites composed of minute tabular crystals. Crystals tabular (001) and elongated [100] at times (artificial).
Crystal structure
Chemical composition
Synonyms
- Mercalliet
In other languages
- German
- Mercallit
- Italian
- Mercallite
Classification
Strunz
10th ed.7.AD.10
- 7SulfatesClass
- 7.ASulfates (selenates, etc.) without additional anions, without H2ODivision
- 7.ADWith only large cationsGroup
- 7.AD.10MercalliteSpecies
Dana
8th ed.28.01.01.01
- 28Anhydrous Acid and Normal SulfatesClass
- 28.01Anhydrous Acid SulfatesType
- 28.01.01— unnamed intermediate level —Group
- 28.01.01.01MercalliteSpecies
CIM
—25.1.5
- 25SulphatesClass
- 25.1Sulphates of the alkali metals and ammoniumGroup
- 25.1.5MercalliteSpecies
Literature, links & citation
Citations
- 1856Marignac, J.C. (1856) Annales des mines [5]: 9: 6. (artificial)
- 1856Marignac, J.C. (1856) Oeuvres: 1: 436. (artificial)
- 1858Lang (1858) Konigliche Akademie der Wissenschaften, Vienna, Sitzber.: 51: 95.
- 1904Gossner, B. (1904) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 39: 381.
- 1908Groth, P. (1908) Chemische Krystallographie Vol. 2. Wilhem Engelmann.
Cite this entry
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Mercallite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/mercallite-2646},
note = {Accessed 2026-05-11}
}